Structure and Optical Properties of Mechanically Robust Lead Halide Perovskite Supercrystals
Marcus Scheele a
a Institute of Physical and Theoretical Chemistry, Eberhard Karls University of Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
B.8 Emergent Properties in Nanomaterials: Synthesis, Phenomena, and Applications - #EmergentNano
València, Spain, 2025 October 20th - 24th
Organizers: Dmitry Baranov and James Utterback
Invited Speaker, Marcus Scheele, presentation 251
Publication date: 17th July 2025

Ordered arrays of nanocrystals, called supercrystals, have attracted significant attention owing to their unique collective quantum effects arising from the coupling between neighboring nanocrystals. In particular, lead halide perovskite nanocrystals are widely used because of the unique combination of the optical properties and faceted cubic shape, which enables the formation of highly-ordered supercrystals. The most frequently used method for the fabrication of perovskite supercrystals is based on self-assembly of nanocrystals from solution via slow evaporation of the solvent. However, the supercrystals produced with this technique grow in random positions on the substrate. Moreover, they are mechanically too soft to be easily manipulated with microgrippers, which hinders their use in applications.

This presentation will detail how mechanically robust supercrystals built from cubic lead halide perovskite nanocrystals are synthesized that can easily be relocated over macroscopic distances into positions and substrates of choice. X-ray nanodiffraction provides details about the local structure of the supercrystals, and fluorescence laser scanning microscopy under applied bias reveals the effect of strong electric fields on the (collective) optical properties of the supercrystals.

The Deutsche Forschungsgemeinschaft (DFG) is acknowledged for funding under grants SCHE1905/15-1 (project Nr. 546072194) and SCHE1905/9-1 (project Nr. 426008387).

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