Publication date: 21st July 2025
Photocatalytic hydrogen production using 2D Ruddlesden-Popper tin iodide perovskites emerges as a promising approach for sustainable energy conversion. However, a key challenge associated with these materials is their susceptibility to degradation due to the oxidation of tin and iodide. In this study, microcrystals of 4-fluorophenethylammonium tin iodide perovskite were synthesized in a mixture of hydroiodic acid (HI) and water, demonstrating long-term photostability and robust photocatalytic hydrogen production via HI splitting. Intermittent light irradiation was found to enhance hydrogen evolution by promoting more efficient charge separation and reducing the accumulation of trapped charge carriers that would otherwise lead to recombination. Notably, reused samples exhibited improved photocatalytic performance over time. Furthermore, degraded samples could be easily regenerated through a simple chemical treatment, restoring their hydrogen production capability. In addition, the use of Sn-based perovskite solar cells as photocathodes in aquous solution for hydrogen generation will be also reported, highlighting the interest of Pb-free perovskites for photocatlytic applications.
We thak the funding of Project 101071010 — OHPERA from the European Innovation Coincil (EIC)