Sn-Based Halide Perovskites for Photocatalytic Applications
Ivan Mora-Seró a
a Institute of Advanced Materials (INAM), Universitat Jaume I (UJI), Castellón de la Plana, 12006, Spain
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
A1 Halide Perovskites - Properties, Synthesis and Advanced Characterization - #PeroProp
València, Spain, 2025 October 20th - 24th
Organizers: Kunal Datta and Selina Olthof
Oral, Ivan Mora-Seró, presentation 256
Publication date: 21st July 2025

Photocatalytic hydrogen production using 2D Ruddlesden-Popper tin iodide perovskites emerges as a promising approach for sustainable energy conversion. However, a key challenge associated with these materials is their susceptibility to degradation due to the oxidation of tin and iodide. In this study, microcrystals of 4-fluorophenethylammonium tin iodide perovskite were synthesized in a mixture of hydroiodic acid (HI) and water, demonstrating long-term photostability and robust photocatalytic hydrogen production via HI splitting. Intermittent light irradiation was found to enhance hydrogen evolution by promoting more efficient charge separation and reducing the accumulation of trapped charge carriers that would otherwise lead to recombination. Notably, reused samples exhibited improved photocatalytic performance over time. Furthermore, degraded samples could be easily regenerated through a simple chemical treatment, restoring their hydrogen production capability. In addition, the use of Sn-based perovskite solar cells as photocathodes in aquous solution for hydrogen generation will be also reported, highlighting the interest of Pb-free perovskites for photocatlytic applications.

We thak the funding of Project 101071010 — OHPERA from the European Innovation Coincil (EIC)

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info