IMPROVED STABILITY OF BiVO4 PHOTOANODES FOR GLYCEROL OXIDATION
Radeya Vasquez a, Ana Gutierrez a, Marco Favaro b, Sixto Gimenez a
a Universitat Jaume I, Institute of Advanced Materials (INAM) - Spain, Avinguda de Vicent Sos Baynat, Castelló de la Plana, Spain
b Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 12203 Berlin, Germany
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
E7 Photoelectrochemical approaches for added-value chemicals and waste valorization - #PecVal
València, Spain, 2025 October 20th - 24th
Organizers: Salvador Eslava, Sixto Gimenez Julia and Ana Gutiérrez Blanco
Oral, Radeya Vasquez, presentation 314
Publication date: 21st July 2025

Bismuth vanadate (BiVO4) is a promising photoactive material for oxidation reactions but is unstable in strongly acidic conditions, which remains a significant challenge, [1][2] particularly for applications like the glycerol oxidation reaction (GOR), [3] which has recently received high interest, since glycerol is a byproduct from the biodiesel industry and can be converted into high-value chemicals through selective oxidation and with a rather low energy input.

In this context, achieving stable photoanode performance at low pH conditions, is crucial for efficient and selective conversion of glycerol into high added-value products, like dihydroxyacetone (DHA), [4][5]. This communication will address our strategy to enhance the stability of BVO photoanodes in acidic solutions, by the deposition of nanometric layers of metal oxides (TiO2, and Al2O3) through atomic layer deposition (ALD). Notably, BVO photoanodes modified with these protection layers demonstrate significantly improved stability, with negliglible loss of performance during at least 12 hours. This research demonstrates a viable strategy for improving the stability of BVO photoanodes in acidic environments, paving the way for more robust and efficient photoelectrochemical glycerol valorization.

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