Antimony Chalcogenide Thin-Film Photovoltaics: Advancing from Material and Device Innovation to Emerging Specialty PV Applications
Nicolae Spalatu a, Athulya Babu Suseela a, Mykhailo Koltsov a, Sajeesh Vadakkedath Gopi a, Robert Krautmann a, Atanas Katerski a, Malle Krunks a, Ilona Oja Acik a
a Tallinn University of Technology, Department of Materials and Environmental Technology, Ehitajate tee 5, 19086 Tallinn, Estonia.
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
A6 Advanced materials and device architectures for Transparent PV - #TransparentPV
València, Spain, 2025 October 20th - 24th
Organizers: Aldo Di Carlo and Alejandro Perez-Rodriguez
Invited Speaker, Nicolae Spalatu, presentation 347
Publication date: 21st July 2025

Development of new photovoltaic (PV) technologies based on novel green materials with higher efficiency and lower cost options could create a new industry with independent supply chains, foster IoT market diversification, and attenuate market volatility. Sb-chalcogenide compounds have recently gained increasing attention as defect tolerant, non-toxic and highly stable materials for earth abundant thin film polycrystalline PV technology.  Despite of their recent addition to the thin film device value chain, efficiency values of these materials have climbed rapidly and are now approaching 11%. Yet despite of this rapid progress, there is still headroom to increase performance significantly by addressing both, fundamental material challenges and innovation in device designing and development. This presentation will review the most relevant progress achieved for Sb-chalcogenides thin film PV, with the emphasis on key processing strategies to optimize absorber material and thin film solar cells properties (doping and alloying), understanding of buried interfaces and push the boundaries of understanding and performance. Based on the state-of-the art progress in performance of emerging Sb-chalcogenide PV materials, a roadmap of customized PV application variability, including semitransparent and tandem PV devices for BIPV, PIPV and IoT markets will be presented.

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