BiVO4 photoanodes for upscalable solar fuel production
Sixto Gimenez a
a Institute of Advanced Materials (INAM-UJI), Universitat Jaume I, Castelló, 12071, Spain
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
E6 Photo-assisted chemical reactions: materials, characterization and mechanisms - #PhotoChem
València, Spain, 2025 October 20th - 24th
Organizers: Josep Albero Sancho and Menny Shalom
Invited Speaker, Sixto Gimenez, presentation 373
Publication date: 21st July 2025

The global challenges of climate change and energy availability demand urgent solutions to reduce our dependence on fossil fuels and promote clean, renewable energy alternatives. Among emerging technologies, (photo)electrocatalysis stands out as a promising pathway to produce sustainable fuels and chemicals with minimal environmental impact, supporting the shift toward a low-carbon future.[1]

This presentation focuses on our recent efforts on the development of bismuth vanadate (BiVO) as a photoanode material for solar-driven oxidation reactions. BiVO offers multiple advantagesit is composed of relatively Earth-abundant elements, has chemical stability, favorable electronic properties for charge separation, and remains cost-effective. Nevertheless, its practical application is hindered by intrinsic limitations, including sluggish water oxidation kinetics, rapid charge recombination, low charge carrier mobility, and limited carrier diffusion lengths (~70 nm).[2]

To overcome these challenges, we introduce nanostructuring strategies that significantly enhance the material’s performance.[4-5] By integrating organic hole transport layers and catalytic coatings to form efficient heterostructures, we achieve improved activity and long-term stability. Importantly, these enhancements are compatible with scalable production methods: we demonstrate a continuous flow-synthesis approach for fabricating large-area photoelectrodes (up to 50 cm2) with competitive performance.[3] A central aspect of our research is gaining mechanistic insight. Using a suite of spectroscopic techniques, we probe charge carrier dynamics and interfacial processes, revealing the factors that govern device behavior and identifying pathways for further optimization.[6]

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info