Surface Modification of Cu Cathode Using Ionization Tendency with Ag2SO4 for Electrochemical CO2 Reduction
Kazuki Koike a b, Takeharu Murakami b, Kentaro Inoue a, Takayo Ogawa b, Katsushi Fujii b, Satoshi Wada b, Atsushi Ogura a c
a Meiji University, 101-8301, Japón, Chiyoda City, Japan
b RIKEN RAP
c MREL
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
E2 Experimental and Theoretical Advances in (Photo)Electrochemical Conversion of CO2 and N2 - #ηPEC
València, Spain, 2025 October 20th - 24th
Organizers: Angelica Chiodoni, Francesca Risplendi and Juqin Zeng
Poster, Kazuki Koike, 449
Publication date: 21st July 2025

Direct air capture and electrochemical reduction of CO2 to industrially useful substances such as ethylene and methane are currently receiving significant attention. Current problems with electrochemical CO2 reduction include a lack of product controllability and long-term stability. Product selectivity depends on the material for the CO2-reducing cathode electrode and the cathode potential during the reaction. The type of metal and its crystal plane significantly influence the product formation. Although product controllability is insufficient, the Cu cathode is attractive due to its high efficiency in producing ethylene, which is an industrially valuable substance used as the precursor for plastics and other applications. Previous studies have proposed adding Ag to Cu [1]. Furthermore, increasing the effective surface area of the projected electrode area to enhance projected current density and reduce the size of the electrolytic cell is also necessary for practical applications.

We devised a method to surface-modify Cu electrodes using ionization tendency with Ag2SO4. Immersing the Cu electrode in sulfuric acid under ultrasonic agitation, with a small amount of Ag2SO4 added to the sulfuric acid, causes the surface of the Cu electrode to dissolve by the ionization tendency, creating numerous nm-sized holes. Furthermore, many reduced Ag particles form several nm-sized particles that cover the Cu electrode surface. This method can simultaneously achieve both the previously studied enhancement of effective electrode surface area and Ag addition. This method has the possibility of enabling increased current throughout the entire electrochemical cell. This study shows the evaluation of the surface morphology for Cu electrodes with and without surface modification by Ag2SO4 under various conditions, including the conditions of the electrode potential and products observed during CO₂ reduction.

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