Transparent conducting polymers based on bisEDOT for enhanced perovskite solar cell performance.
Noemí Farinós Navajas a, Miriam Mínguez Avellán a, Pablo Franco Betancur a, Rafael Abargues López a, Teresa Sanchis Ripolles a, Pablo Pérez Boix b
a Instituto de Ciencia de los Materiales- Universidad de Valencia, Catedrático José Beltrán, 2, 46071, Valencia, Spain
b Instituto de Tecnología Química (ITQ), Universitat Politècnica de València- Consejo Superior de Investigaciones Científicas (UPV-CSIC), València, 46022 Spain
Proceedings of MATSUS Fall 2025 Conference (MATSUSFall25)
A4 Fundamental understanding of halide perovskite materials and devices - #PeroFun
València, Spain, 2025 October 20th - 24th
Organizers: Krishanu Dey, Iván Mora-Seró and Yana Vaynzof
Poster, Noemí Farinós Navajas, 474
Publication date: 21st July 2025

The design of novel transparent conducting polymers continues to attract considerable attention due to their versatility in optoelectronic technologies. In this work, we present a new class of bisEDOT-based polymers as promising alternatives to conventional PEDOT:PSS. Our strategy relies on the oxidative in situ polymerization of bis-EDOT, the dimer of 3,4-ethylenedioxythiophene, within a polymethyl methacrylate (PMMA) matrix using Cu(ClO₄)₂ as oxidant. This method produces uniform and highly transparent conducting films characterized by improved electrical conductivity, robust mechanical properties, and excellent processability. The resulting composites can be formulated as inks, enabling precise control over film thickness, tunable conductivity, and high optical transmittance across the visible and near-infrared regions. Importantly, the material is compatible with diverse solvents and additives, ensuring integration with perovskite-based devices. Performance assessments highlight superior charge-transport characteristics and enhanced long-term stability, establishing these polymers as strong candidates for hole-transport layers in tin- and lead-based perovskite solar cells. Beyond photovoltaics, the straightforward and scalable nature of this synthetic route broadens its applicability to flexible electronics, OLEDs, sensing platforms, and transparent electrodes. This approach thus represents a versatile pathway toward next-generation functional materials for energy and optoelectronic applications.

 

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info