Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.381
Publication date: 16th December 2024
Organic semiconductors are an emerging class of materials with various optoelectronic applications and huge potential in supporting the development of greener electronics.In my talk, I will introduce sustainable routes to manufacture solution-processed organic photovoltaics. Most organic electronic devices are fabricated from halogenated and non-halogenated aromatic solvents, primarily due to the good solubility of the materials in the solvents and the ideal microstructure/crystallinity they are forming in those. For large-scale production and further commercialisation, this is a key limitation, as they can be carcinogenic or toxic to the human reproductive systems and negatively impact the environment. Here, I will show high-performing organic solar cells developed from novel, more sustainable organic semiconductors (in terms of less waste during synthesis and less energy consumption) as well as eco-friendly solvents. In particular, solvents derived from biomass have been explored for their application in delivering high-performing organic photovoltaics based on PTQ10:Y12 and FO6-T:Y12 with PCE > 14%.
Finally, I will discuss possible degradation mechanisms of the bulk heterojunction systems containing Y6 or Y12 as the acceptor, after degradation with indoor and outdoor light. A combination of electrical, morphological, and spectroscopic techniques were used to evaluate the degradation pathways of the OPVs.