In-Situ Morphological Analysis of Blade Coated Semi-transparent Organic Solar Cells
Emma Spooner a, Rachel Kilbride b, Daniel Toolan c, Matthew Halsall a, Iain Crowe a
a Photon Science Institute, University of Manchester, Oxford Road, Manchester M13 9PL, UK
b Department of Chemistry, The university of Sheffield
c Department of Materials, The University of Manchester, Oxford Road, United Kingdom
Materials for Sustainable Development Conference (MATSUS)
Proceedings of MATSUS Spring 2025 Conference (MATSUSSpring25)
Understanding success of OSCs: stability and efficiency - #SuccessOPV
Sevilla, Spain, 2025 March 3rd - 7th
Organizers: Tracey Clarke and Vida Engmann
Oral, Emma Spooner, presentation 629
DOI: https://doi.org/10.29363/nanoge.matsusspring.2025.629
Publication date: 16th December 2024

Whilst organic solar cells (OSCs) have now reached efficiencies necessary for commercialization, their current high cost is prohibitive for most applications. One exception to this is semi-transparent OSCs, where the tuneable absorption of the active layer can be uniquely exploited to create power generating, semi-transparent energy sources. These hold great potential for building integrated photovoltaics, and net-zero architecture. A common way to achieve this transparency is via reduced donor content, in so called ‘dilute donor’ cells.

In this work we explore printing such dilute donor systems, using donor PTQ10 and acceptor Y12, via blade coating; alongside structural analysis to understand the relationship between printing conditions and photovoltaic performance.

We show results from a custom, blade coater setup used to measure in-situ grazing incidence wide angle x-ray scattering (GIWAXS) at the Diamond Light Source synchrotron, under a range of conditions. We see differences in crystallization and drying dynamics depending on stage temperature and donor content, and relate these to device performance for blade coated OSCs. Grazing incidence small angle x-ray scattering (GISAXS) and a range of device based optoelectronic measurements are also shown to provide an overview of structure-function relationships. We believe this work provides an important insight into how blade-coating conditions impact film morphology, and therefore how printing conditions can be designed for optimum semi-transparent OSCs.

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