Novel surface passivation for wide-bandgap perovskites
Charlie Nicholls a b, James Pidgeon b, Alexandra Ramadan b, Robert Oliver a
a School of Chemical, Materials and Biological Engineering, University of Sheffield, Sheffield, S1 3JD
b School of Mathematical and Physical Sciences, University of Sheffield, Sheffield, S3 7RH, UK
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
A6 Future of Metal Halide Perovskites: Fundamental Approaches and Technological Challenges
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Annalisa Bruno, Sofia Masi and Pablo P. Boix
Oral, Charlie Nicholls, presentation 070
Publication date: 15th December 2025

Improving the efficiency of solar cells is the most effective route to reduce the levelised cost of electricity, and hence accelerating installations. Tandem structures offer a route to higher efficiencies (>35%) compared with single junction cells[1]. The tuneable bandgap and long charge-carrier lifetimes of metal halide perovskites make them ideal candidates for use as the top cell in tandem architectures, however their poor stability and large interfacial energetic losses complicate commercialisation[2]. 

Passivating these interfaces is effective in energetic loss mitigation although control over repeatability can be challenging. We have developed a novel passivation route that delivers increased control in passivation efficacy, observing strong enhancements to the perovskite radiative efficiency and photoluminescence lifetimes. Using our home-built stroboscopic scattering microscope (stroboSCAT), we show that the energy transfer dynamics are enhanced in the passivated samples, elucidating microscale insights into the passivation mechanism. Finally, we fabricated full photovoltaic devices that demonstrated successful interfacial passivation with increased repeatability compared with vapour passivation, highlighting the benefit of our approach.

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