Publication date: 15th December 2025
Oxygen stoichiometry in mixed ionic-electronic conductors (MIECs) can be used to control a wide range of materials functionalities, from electrical conductivity to optical and magnetic properties [1]. Moreover, by appropriately choosing MIEC materials with a wide electrochemical stability window, oxygen incorporation/release can be used for charge storage, in analogy with Li-ion battery electrodes. In the present contribution, I will show our recent results related to precise oxygen control in MIEC thin films using advanced electrochemical methods, and demonstrate how this strategy can be implemented for the precise tuning of materials functionalities and for the realization of new generation of oxygen-based devices including an all-solid-state oxygen-ion battery (OiB) [2]. These batteries can deliver continuous and reliable operation in intermediate and high temperature environments (>250 ºC), where state-of-the-art Li-based devices fall short, and they present high stability towards a variety of environmental conditions – including oxygen and humidity, while delivering competitive performance (OCV > 1V, electrode capacity > 60 mAh g-1). Advances in technology development, including electrolyte miniaturization, electrode engineering, and technology scale-up, which are being achieved within the European project “OxyBatt”, will be shown.
This project received funding by the European Union under HorizonEU research and innovation program OxyBatt (101158721)
