Engineering oxygen stoichiometry in mixed conductors for next-generation energy devices
Federico Baiutti a, Andrea Turino a, Paul Nizet a, Francesco Chiabrera a, Alexander Schmid b, Juergen Fleig b, Albert Tarancon a c
a IREC, Catalonia Institute for Energy Research, C/ Jardins de les Dones de Negre 1, Barcelona 08930, Spain
b Technical University of Vienna, Wiedner Hauptstraße 8-10, Austria
c ICREA, Passeig Lluis Companys, 23, Barcelona 08010, Spain
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
F5 Lithium Batteries and Beyond: From Fundamentals to Materials Discovery
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Chia-Chin Chen and Gints Kucinskis
Oral, Federico Baiutti, presentation 143
Publication date: 15th December 2025

Oxygen stoichiometry in mixed ionic-electronic conductors (MIECs) can be used to control a wide range of materials functionalities, from electrical conductivity to optical and magnetic properties [1]. Moreover, by appropriately choosing MIEC materials with a wide electrochemical stability window, oxygen incorporation/release can be used for charge storage, in analogy with Li-ion battery electrodes. In the present contribution, I will show our recent results related to precise oxygen control in MIEC thin films using advanced electrochemical methods, and demonstrate how this strategy can be implemented for the precise tuning of materials functionalities and for the realization of new generation of oxygen-based devices including an all-solid-state oxygen-ion battery (OiB) [2]. These batteries can deliver continuous and reliable operation in intermediate and high temperature environments (>250 ºC), where state-of-the-art Li-based devices fall short, and they present high stability towards a variety of environmental conditions – including oxygen and humidity, while delivering competitive performance (OCV > 1V, electrode capacity > 60 mAh g-1). Advances in technology development, including electrolyte miniaturization, electrode engineering, and technology scale-up, which are being achieved within the European project “OxyBatt”, will be shown.

 

This project received funding by the European Union under HorizonEU research and innovation program OxyBatt (101158721)

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