Publication date: 15th December 2025
Elaborate chemical synthesis methods enable the production of various types of inorganic nanocrystals (NCs) with uniform shapes and size distributions. However, how can we synthesize NCs with thermodynamically metastable phases or highly complex structures? Transforming pre-synthesized NCs through elemental substitutions—such as ion-exchange reactions for ionic NCs [1–4] and galvanic replacement reactions for metallic NCs—can overcome the limitations of conventional one-step syntheses. In particular, ion-exchange reactions have been extensively studied using numerous combinations of foreign ions and ionic NCs of various shapes. The optical properties of the resulting ionic NCs and their assemblies can be readily tuned over a wide range [5]. Here, we focus on full and partial ion-exchange reactions of ionic NCs and their assemblies, emphasizing key aspects such as the preservation of morphology and dimensions [2,3,6,7]. Finally, we discuss the formation of unprecedented Z3-type FePd₃ NCs by substituting a small amount of Pd with In, based on the interelement miscibility among Fe, Pd, and In [8–10].
This work was financially supported by the Japan Science and Technology Agency (JST)– Core Research for Evolutionary Science and Technology (CREST) (Grant No. JPMJCR21B4) and Japan Society for the Promotion of Science (JSPS) KAKENHI for Scientific Research S (Grant No. JP24H00053).
