Direct synthesis of conductive CdSe quantum dots inks
Xavier Kirchherr a, Loredana Protesescu a
a Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 3, Groningen, 9747AG, The Netherlands.
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
C4 Precision synthesis of nanocrystals and nanochemistry
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: ZHANZHAO LI, Baowei Zhang and Juliette Zito
Oral, Xavier Kirchherr, presentation 219
Publication date: 15th December 2025

Quantum dots have opened the way to new technologies due to their unique tunable photoelectronic properties. To fabricate devices, they are processed as concentrated inks with short ligands after replacing the insulating ligands used in their colloidal synthesis. Cadmium selenide (CdSe) is a ubiquitously studied quantum dot system with extensive synthetic and surface chemistry understanding. Yet no direct ink synthesis has been developed other than aqueous routes that show poor photoluminescence.

In this work, we develop a direct synthesis of inorganic-passivated CdSe QDs in polar solvents. We identify a thermally activated growth through magic-size clusters, which follows two-step nucleation and growth kinetics. Through liquid state 113Cd NMR, we show that highly Lewis basic solvents and weakly-coordinating ions favour the formation of high-quality CdSe nanocrystals. Surface characterisations, including ζ-potential, solid-state NMR, Raman and IR spectroscopy, reveal a disordered surface rich in cadmium-oxygen bonds, compromising the photoluminescence and chemical stability of the quantum dots. These results reinvigorate polar synthesis routes for quantum dots and improve our understanding towards a one-step synthesis of inorganic-passivated quantum dots.

Kaloyan Milanov, Simon Böhme, Anuluxan Santhiran, Shawon Abu, Aaron Rossini, Maksym Kovalenko

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info