Multimodal microscopy of nanoscale photovoltaic function in hybrid perovskites
Stefan Weber a
a Institute for Photovoltaics(ipv), University of Stuttgart,70569 Stuttgart, Germany;
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
G5 In Situ and Operando Characterization Across Disciplines: Advanced Lab-Based Techniques for Energy Conversion Research
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Johanna Eichhorn and Verena Streibel
Invited Speaker, Stefan Weber, presentation 227
Publication date: 15th December 2025

Hybrid metalhalide perovskites (MHPs) promise lowcost, highefficiency solar cells, yet their macroscopic performance is limited by loss pathways that originate in nano and microscale structures. Thus, to understand MHP materials requires the characterization of the many nano- and microscale structures; from sub-granular twin domains, over grain boundaries and interfaces to lateral variations in crystal grains orientations and facets. Electrical SPM operation modes like Kelvin probe force microscopy (KPFM) or conductive atomic force microscopy are ideally suited to decipher these structure-function relationships. In this presentation, I will present some of our recent activities in the development of specialized scanning probe microscopy methods to study hybrid perovskite materials.

As one single measurement technique cannot capture the full picture, we develop a combined opticalscanningprobe platform that integrates spatially resolved photoluminescence (PL), timeresolved PL (TRPL) and electrical scanning probe microscopy (Kelvinprobe force microscopy, conductive AFM and nanoscale surfacephotovoltage spectroscopy). This multimodal microscope allows simultaneous measurements of the same region with diffractionlimited confocal PL spectroscopy (≈300 nm lateral resolution), time-resolved photoluminescence (TRPL, time-resolution ~ps) and quantitative electrical AFM (10-20 nm lateral resolution).  This nanoscale photovoltaics lab on a tip therefore bridges the longstanding divide between optical spectroscopy and nanoscale electrical probing. By delivering a correlative view of bandgap emission, carrier dynamics and electrostatic landscape, it enables quantitative identification of the dominant nanoscale loss mechanisms that limit MHP solarcell performance. The approach can be extended to other emerging photovoltaic materials and offers a powerful tool for rational engineering of grain boundaries, transport layers and compositional stability. 

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