Publication date: 15th December 2025
Hybrid metal halide perovskites are the most promising candidates for high-performance multi-junction solar cells that surpass the fundamental efficiency limits of traditional devices. Furthermore, their bandgap tunability, high radiative quantum yields, and defect tolerance also make them excellent light emitters. Two-dimensional (2D) perovskite semiconductors have promising prospects for enhancing the stability of perovskite-based photovoltaic devices. In addition, these low-dimensional materials with electronic confinement offer further opportunities in light emission and quantum technologies. However, their technological applications still require a comprehensive understanding of the nature of charge carriers and their transport mechanisms.
This talk will show how time-resolved optical spectroscopy can be employed to investigate charge-carrier dynamics, exciton formation dynamics, transport properties and transfer mechanisms in perovskite semiconductors. We will see how 2D perovskites show band transport with high in-plane mobilities that give rise to efficient long-range conductivity, despite quantum confinement. We show how the organic cation moderates the coupling of charge carriers to optical phonon modes, impacting the charge-carrier mobilities. We demonstrate the exciton formation dynamics over the picosecond timescale using a combination of terahertz and transient absorption spectroscopy, revealing a long-living population of free charge-carriers that greatly surpasses the theoretical predictions of the Saha equation even at temperatures as low as 4K. Finally, we look at charge dynamics in mixed-phase 2D/3D perovskite films, investigating the effect of different organic cations and additives introduced in the fabrication process. Using a combination of experimental investigations and numerical modelling, we show the interplay of trap-assisted recombination and charge transfer dynamics, and investigate the existence of selective hole and electron transfer pathways.
