Charge carrier dynamics in mixed-phase and low dimensional perovskites
Silvia Motti a
a School of Physics & Astronomy, University of Southampton, SO17 1BJ, Southampton, United Kingdom
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
A5 From halide perovskites to perovskite-inspired materials – Synthesis, Modelling and Application
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Gustavo de Miguel, Lorenzo Malavasi and Isabella Poli
Invited Speaker, Silvia Motti, presentation 242
Publication date: 15th December 2025

Hybrid metal halide perovskites are the most promising candidates for high-performance multi-junction solar cells that surpass the fundamental efficiency limits of traditional devices. Furthermore, their bandgap tunability, high radiative quantum yields, and defect tolerance also make them excellent light emitters. Two-dimensional (2D) perovskite semiconductors have promising prospects for enhancing the stability of perovskite-based photovoltaic devices. In addition, these low-dimensional materials with electronic confinement offer further opportunities in light emission and quantum technologies. However, their technological applications still require a comprehensive understanding of the nature of charge carriers and their transport mechanisms.

This talk will show how time-resolved optical spectroscopy can be employed to investigate charge-carrier dynamics, exciton formation dynamics, transport properties and transfer mechanisms in perovskite semiconductors. We will see how 2D perovskites show band transport with high in-plane mobilities that give rise to efficient long-range conductivity, despite quantum confinement. We show how the organic cation moderates the coupling of charge carriers to optical phonon modes, impacting the charge-carrier mobilities. We demonstrate the exciton formation dynamics over the picosecond timescale using a combination of terahertz and transient absorption spectroscopy, revealing a long-living population of free charge-carriers that greatly surpasses the theoretical predictions of the Saha equation even at temperatures as low as 4K. Finally, we look at charge dynamics in mixed-phase 2D/3D perovskite films, investigating the effect of different organic cations and additives introduced in the fabrication process. Using a combination of experimental investigations and numerical modelling, we show the interplay of trap-assisted recombination and charge transfer dynamics, and investigate the existence of selective hole and electron transfer pathways.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info