Publication date: 15th December 2025
Conventional blue-emitting materials often struggle to simultaneously achieve narrow emission linewidth, chemical stability, and compatibility with thin-film device fabrication. These limitations are especially pronounced in solution-processed systems, where uncontrolled nucleation frequently leads to rough and non-uniform films. Here, we present a vapor-phase strategy to synthesize uniform, covalently bonded organic-inorganic hybrid AgSePh thin films. By sequentially depositing metallic Ag and diphenyldiselenide (Ph2Se2) in the vapor phase and inducing amine-assisted crystallization, we obtain high-quality films that preserve the intrinsic deep-blue emission characteristics of AgSePh. The resulting films exhibit a peak emission at 466 nm with a narrow full width at half maximum (FWHM) of 16.6 nm, satisfying the high color-purity requirements for advanced display technologies. Using these films, we demonstrate the first AgSePh-based blue light-emitting diodes, confirming stable and intrinsic electroluminescence (EL) from this material. This work provides a practical route for integrating insoluble metal-organic chalcogenide (MOC) emitters into thin-film devices and highlights their potential as a robust platform for next-generation high color-purity blue displays.
This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (RS-2023-00283597, RS-2024-00408951).
