Sustainable electrodes for electrophysiological acquision
Matías Ignacio Ceballos Hernández a, Esma ISMAILOVA a, Wei-Ting Ting a, Suzanne Thummler b
a Ecole des mines de saint Etienne, Route de Mimet, Gardanne, France
b Université Côte d'Azur, France, 28 Avenue de Valrose, Nice, France
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
I1 Novel materials and strategies for organic bioelectronics
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Miryam Criado-Gonzalez, Alberto Scaccabarozzi and Gabriele Tullii
Oral, Matías Ignacio Ceballos Hernández, presentation 284
Publication date: 15th December 2025

Wearable biosensing routines use skin-contact electrodes. Traditional gel-based electrodes dry out over time, lose performance, and contribute to substantial electronic waste generation. [1] In response, we developed soft, breathable electrodes made of porous PDMS sponges coated with PEDOT:PSS (poly(3.4-ethylenedioxythiophene): poly(styrenesulfonate))— a conducting polymer forming a gel-free device that conforms naturally to the skin.[2,3] This approach makes use of both commercial and recovered PEDOT:PSS, from spent formulations, towards sustainable sensor manufacturing. Additionally, an original way of sponge structure fabrication was applied via a sugar-templating method, achieving a porous network that enhances their conformal contact and breathability.[4] The conductive coating is then applied through dip-coating and chemical crosslinking to ensure its strong adherence. Electrochemical impedance spectroscopy and long-term stability testing show that the electrodes from the recycled and commercial formulations uphold low skin–electrode impedance even after extended wear (10 hours). Simultaneous heart and brain wave recordings with both electrode types demonstrated high-fidelity signal acquisition and signal-to-noise ratios compared to gold standard Ag/AgCl electrodes. The stable performance over hours of continuous use confirms the sponge electrode’s capacity to perform in long-term, wearable monitoring. By merging comfort, performance, and recyclability, this work paves the way for the next generation of sustainable wearable sensor manufacturing.

This work was supported by the French National Research Agency (ANR) under the ANR-AI-WEAR project (ANR-23-CE19-0032), whose financial contribution is gratefully acknowledged. The authors also thank the staff of the Centre Microélectronique de Provence (CMP) at École des Mines de Saint-Étienne for their technical assistance. Part of this work was performed with the support of the MicroPacks platform at the Centre Microélectronique de Provence (Project funded by the European Regional Development Fund, the French state and local authorities).

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