Correlative Atomic Force Microscopy to Understanding Local Charge Transport in Photoanodes
Sven Doll a, Johanna Eichhorn a
a Physics Department, TUM School of Natural Sciences, Technical University of Munich, Am Coulombwall 4, 85748 Garching, Germany
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
G6 Operando and Correlative Characterization of Sustainable Materials and Interfaces
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Florian Hausen and Svetlana Menkin
Oral, Sven Doll, presentation 317
Publication date: 15th December 2025

Efficient photosystems for solar-to-chemical energy conversion are often based on  nanostructured semiconductor architectures. In these material systems, the nanoscale  
properties frequently dominate the performance at the macroscale. Therefore, local  understanding of their charge transfer and transport properties is decisive for optimizing  
their efficiency and stability.


To this end, we correlate Kelvin probe force microscopy (KPFM) and (photo)conductive  atomic force microscopy (AFM) to study the local band bending, charge accumulation,  
as well as variations in the generated surface photovoltage and (photo)conductivity. However, analyzing nanostructured materials with complex morphologies is not trivial,  as effects such as topographic crosstalk or surface potential averaging can significantly  influence the results obtained with different techniques. To overcome these issues, we  leverage 2nd eigenmode and heterodyne KPFM measurements with improved resolution  and sensitivity compared to conventional frequency- and amplitude-modulated  techniques. For (photo)conductive AFM, a special tapping mode with simultaneous  current measurements is used to reduce sample and probe damage, enabling  measurements on polycrystalline films. For BiVO4, one of the most extensively studied  metal oxide photoanode materials, we compare different KPFM modes and correlate the  results with local conductivity measurements to gain insights into local semiconductor  properties at grain boundaries or different crystal facets. Overall, the gained nanoscale  insights will put forward the development of rational design strategies to enhance the  macroscale durability and efficiency of solar energy conversion systems.

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