Exciton-plasmon interactions in superlattices of CsPbBr3 nanocrystals and Au nanoparticles
Aliki Souzou a, Mariia Svyrydenko b c, Kyriacos Georgiou d, Paris Papagiorgis a, Chenglian Zhu b c, Maryna Bodnarchuk b c, Maksym Kovalenko b c, Grigorios Itskos a
a Experimental Condensed Matter Physics Laboratory Department of Physics, University of Cyprus, Nicosia 1678, Cyprus
b Laboratory for Thin Films and Photovoltaics Empa-Swiss Federal Laboratories for Materials Science and Technology Dübendorf CH-8600, Switzerland
c Institute of Inorganic Chemistry, Department of Chemistry and Applied Bioscience, ETH Zürich, CH-8093, Zürich, Switzerland
d Laboratory of Ultrafast Science, Department of Physics, University of Cyprus, Nicosia 1678, Cyprus
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
H2 Halide perovskites for quantum technologies
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Quinten Akkerman, Simon Boehme and Maksym Kovalenko
Oral, Aliki Souzou, presentation 369
Publication date: 15th December 2025

The assembly of monodisperse nanocrystals (NCs) into long-range ordered superlattices (SLs) provides a platform for engineering materials with programmable and distinct optoelectronic properties compared to those of the constituent building blocks [1]. SLs that integrate NCs of different materials can unite the different functionalities and generate new light-matter interactions [2], expanding the potential for integration into the next-generation optoelectronic devices. This work studies the novel collective optical properties in binary SLs comprising of cubic CsPbBr3 NCs co-assembled with spherical Au nanoparticles (NPs). The study reveals modifications in the absorption and photoluminescence spectra of the binary SLs with reference to the respective single-component CsPbBr3 SLs, attributed to electronic interactions between the nanocrystal excitons and the localized surface plasmons. The dependency of the collective optical properties to the size of the nanocrystal building blocks and the perovskite – plasmonic intercomponent distance is also presented.

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