Resonant Cavity Enhanced Visible Light Photocatalysis
Beatriz de Sola a, Laura Caliò a, Manuel Romero a, Miriam Herrero-Collado b, Mauricio E. Calvo a, Hernán Míguez a
a Instituto de Ciencia de Materiales de Sevilla (CSIC-US), ES, Calle Américo Vespucio, 49, Sevilla, Spain
b Universidad de Cádiz, Facultad de Ciencias. Campus Rio San Pedro, Puerto Real, Spain
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
E3 Photocatalysis for solar fuel and chemical synthesis
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Virgil Andrei and Sixto Gimenez Julia
Oral, Beatriz de Sola, presentation 379
Publication date: 15th December 2025

Herein, we report a novel approach to enhance the photocatalytic degradation of organic pollutants under visible light mediated by nanocrystalline TiO₂ (nc-TiO2) films1. This enhancement results from embedding a nc-TiO₂ film in a Fabry–Perot optical resonator. This approach significantly improve the nc-TiO₂ absorption in the visible range, enabling efficient activation under narrowband LED illumination and simulated solar light. The nanoporous system allows infiltration of methylene blue aqueous solutions, providing a versatile platform for environmental remediation. Photodegradation kinetic was systematically studied at different wavelengths (385 nm, 405 nm), revealing an improvement up to 200% of the kinetic constant compared to conventional TiO₂ films. It was found that the incidence angle critically influences the coupling between resonator optical modes and LED irradiance, offering a new degree of control over photocatalytic performance. Photodegradation kinetics of methylenen blue under a solar simulator were also studied, revealing a higher rate in the case of the optical cavity. This work illustrates how optical engineering can synergize with material chemistry to advance light-driven pollutant degradation. Our findings demonstrate that optical resonator-assisted TiO₂ films effectively overcome the inherent limitations of conventional photocatalysts under visible light. This strategy opens up new opportunities for efficient solar-driven water treatment and a range of other environmental remediation applications by tailoring absorption through resonant structures and optimising illumination parameters.

 

1 B. de Sola, L. Caliò, M. Romero, M. Herrera-Collado, M. Calvo, H. Míguez. Nanocrystallline TiO2 based Fabry Pérot Resonators for Enhanced Visible Light Photocatalysis. In preparation.

These results are part of grant PRE2021-098085, funded by MCIN/AEI/10.13039/501100011033 and FSE+. Financial support was also received from the Spanish Ministry of Science and Innovation under grants PID2020-116593RB-I00 funded by MCIN/AEI/ 10.13039/501100011033, and PID2023-149344OB-I00 funded by MCIU/AEI/10.13039/501100011033 and FEDER, EU.  

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