Publication date: 15th December 2025
Herein, we report a novel approach to enhance the photocatalytic degradation of organic pollutants under visible light mediated by nanocrystalline TiO₂ (nc-TiO2) films1. This enhancement results from embedding a nc-TiO₂ film in a Fabry–Perot optical resonator. This approach significantly improve the nc-TiO₂ absorption in the visible range, enabling efficient activation under narrowband LED illumination and simulated solar light. The nanoporous system allows infiltration of methylene blue aqueous solutions, providing a versatile platform for environmental remediation. Photodegradation kinetic was systematically studied at different wavelengths (385 nm, 405 nm), revealing an improvement up to 200% of the kinetic constant compared to conventional TiO₂ films. It was found that the incidence angle critically influences the coupling between resonator optical modes and LED irradiance, offering a new degree of control over photocatalytic performance. Photodegradation kinetics of methylenen blue under a solar simulator were also studied, revealing a higher rate in the case of the optical cavity. This work illustrates how optical engineering can synergize with material chemistry to advance light-driven pollutant degradation. Our findings demonstrate that optical resonator-assisted TiO₂ films effectively overcome the inherent limitations of conventional photocatalysts under visible light. This strategy opens up new opportunities for efficient solar-driven water treatment and a range of other environmental remediation applications by tailoring absorption through resonant structures and optimising illumination parameters.
1 B. de Sola, L. Caliò, M. Romero, M. Herrera-Collado, M. Calvo, H. Míguez. Nanocrystallline TiO2 based Fabry Pérot Resonators for Enhanced Visible Light Photocatalysis. In preparation.
These results are part of grant PRE2021-098085, funded by MCIN/AEI/10.13039/501100011033 and FSE+. Financial support was also received from the Spanish Ministry of Science and Innovation under grants PID2020-116593RB-I00 funded by MCIN/AEI/ 10.13039/501100011033, and PID2023-149344OB-I00 funded by MCIU/AEI/10.13039/501100011033 and FEDER, EU.
