Publication date: 15th December 2025
Hybrid Sn–Pb perovskite solar cells are promising candidates for tandem photovoltaic applications; however, their performance is frequently constrained by pronounced photovoltage loss and limited operational stability, primarily arising from interfacial recombination and poorly controlled crystallization processes. In this talk, I will present our systematic strategy to regulate interfacial recombination and crystallization dynamics through targeted interface engineering and growth modulation. Specifically, dedoping PEDOT:PSS effectively reduces interfacial energy mismatch and suppresses non-radiative recombination, enabling more efficient hole extraction and a marked enhancement in open-circuit voltage.[1] Further modification using cPTANMe as a tailored hole transport layer improves interfacial energetics and charge selectivity, minimizing recombination losses at the perovskite/HTL interface. [2] In parallel, a fullerene derivative is introduced as an additive to modulate crystallization behavior, refine film morphology, and stabilize the perovskite lattice, thereby mitigating interfacial degradation and enhancing device durability. The synergistic control of charge-selective interfaces and crystal growth pathways not only leads to simultaneous improvements in photovoltage and operational stability, but also provides fundamental insight into the voltage–stability trade-off in hybrid Sn–Pb perovskite systems. These findings establish practical design principles for engineering high-performance and durable narrow-bandgap absorbers, paving the way toward more efficient and reliable next-generation tandem photovoltaic technologies.
C.-T. L. acknowledges the support from the National Science and Technology Council (114-2628-E-005 -001 -), and the Innovation and Development Centre of Sustainable Agriculture from The Featured Areas Research Centre Program within the framework of the Higher Education Sprout Project by the Ministry of Education (MOE) in Taiwan.
