Improving the Performance and Stability of Perovskite Solar Cells via Interface Engineering
Saif Haque a
a Department of Chemistry, Imperial College London Molecular Sciences Research Hub, White City Campus 80 Wood Lane, London W12 0BZ, UK
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
A2 Progress in Narrow-Bandgap Perovskites: Fundamentals and Optoelectronic Applications
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Luis Lanzetta and Tom Macdonald
Invited Speaker, Saif Haque, presentation 529
Publication date: 15th December 2025

The development of perovskite solar cells (PSCs) has gone from strength to strength over the last decade, enabling low-cost, flexible and high-efficiency photovoltaic devices. However, long term device stability remains a challenge for the widespread implementation of this highly promising technology. In this talk I will present our recent work this area focused on addressing the critical stability challenges associated with spiro-OMeTAD based n-i-p configuration devices and reliance on hygroscopic lithium salts. I will also discuss our recent work on identifying iodine induced degradation pathways at hole transport layer / perovskite heterojunctions as well as additive engineering approaches to mitigate the harmful effect of iodine on materials and device performance. Finally, I will present our recent work on the design and application of self-assembled molecules SAMs as hole extraction layers for tin-based perovskite solar cells. The advances reported herein highlight how the combination of chemical design / synthesis and advanced optical & optoelectronic characterization can be employed to help guide the design of perovskite heterojunctions and devices with high performance and stability.

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