Publication date: 15th December 2025
The development of perovskite solar cells (PSCs) has gone from strength to strength over the last decade, enabling low-cost, flexible and high-efficiency photovoltaic devices. However, long term device stability remains a challenge for the widespread implementation of this highly promising technology. In this talk I will present our recent work this area focused on addressing the critical stability challenges associated with spiro-OMeTAD based n-i-p configuration devices and reliance on hygroscopic lithium salts. I will also discuss our recent work on identifying iodine induced degradation pathways at hole transport layer / perovskite heterojunctions as well as additive engineering approaches to mitigate the harmful effect of iodine on materials and device performance. Finally, I will present our recent work on the design and application of self-assembled molecules SAMs as hole extraction layers for tin-based perovskite solar cells. The advances reported herein highlight how the combination of chemical design / synthesis and advanced optical & optoelectronic characterization can be employed to help guide the design of perovskite heterojunctions and devices with high performance and stability.
