Publication date: 15th December 2025
Ammonia (NH3) is a crucial component in the production of fertilisers and various chemicals, yet its traditional industrial synthesis via the Haber-Bosch process is energy-intensive and environmentally impactful [1,2]. As a result, a wide range of alternative sources, other than nitrogen gas (N2), for the synthesis of NH3 has been explored within the community. Electrocatalytic nitrate reduction reaction (NO3--to-NH3) offers a sustainable and decentralised alternative route by utilising renewable electricity to convert abundant NO3- sources, such as agricultural runoff or industrial wastewater, into valuable ammonia [3,4]. However, the development of efficient, durable, and environmentally friendly catalysts for this complex multi-electron transfer process remains a significant challenge. As such, this work presents a study on the development of a flexible, high-performance electrocatalyst composed of molybdenum disulfide (MoS2) and tungsten disulfide (WS2) nanosheets, on a robust reduced graphene oxide (rGO) modified carbon cloth (CC) substrate [5,6]. At the low applied potential of -0.4 V (vs. RHE) and in 0.1 M KOH electrolyte containing KNO3, MoS2/WS2-rGO@CC catalysts exhibited excellent nitrate reduction performance with a high Faradic Efficiency (FE) of ~30.3%, good selectivity for NO3-reduction to N2 (~97.9%), good hindrance to parasitic hydrogen evolution reaction (HER), along with displaying outstanding NH3 yield rate of 50 mg.h-1.mgcat-1. Upon mimicking the neutral-pH environmental conditions of real wastewater outlets, the optimised electrocatalysts were used for NO3-RR in 0.1 M Phosphate Buffer (pH 7) electrolyte containing KNO3, showed an enhanced and stable NH3 yield rate of 206 μg.h-1.mgcat-1 with a ~18.1% FE in a flow system. This unique design of the electrocatalyst took advantage of the high surface area and conductivity of the rGO-modified CC, combined with the enhanced catalytic activity of the MoS2/WS2 heterostructures. In general, this study provides a practical pathway for tailoring 2D materials for application in wastewater treatment and environmental remediation.
This work has been funded by a grant from the Programme Johannes Amos Comenius under the Ministry of Education, Youth and Sports of the Czech Republic (CZ.02.01.01/00/22_008/0004558 Advanced MUltiscLe materials for key Enabling Technologies (AMULET)).
