Synthesis and Catalytic Properties of High Entropy Nanoparticles
Raymond Schaak a
a Penn State University
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
C3 Compositionally Complex Nanocrystals: Synthesis and Application
Barcelona, Spain, 2026 March 23rd - 27th
Organizer: Suvodeep Sen
Invited Speaker, Raymond Schaak, presentation 534
Publication date: 15th December 2025

Nanoparticles of high entropy materials are intriguing catalysts since they combine high surface areas with synergistic effects that arise from the randomization of a large number of elements throughout a crystalline lattice. However, the synthesis of high-quality nanoparticles of high entropy materials can be challenging, particularly for colloidal nanoparticles made in solution. This talk will highlight our recent efforts in synthesizing several different classes of high entropy materials as colloidal nanoparticles, including alloys, intermetallics, sulfides, oxides, and oxyhalides. By studying aliquots extracted during high entropy nanoparticle synthesis, we have been able to generate snapshots of these complex nanochemical reactions. In most cases, we find that colloidal nanoparticles of high entropy materials form stepwise in solution through heterogeneous intermediates, despite generating products that have largely homogeneous co-localization of all constituent elements. This talk will also highlight some of the catalytic properties that emerge from these high entropy nanoparticles, including for hydrogenation, hydrogen evolution, and oxygen evolution.

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