The Role of Double Transport Layers on the Stability and Performance of Perovskite Solar Cells
Joseph Luther a
a National Renewable Energy Lab (NREL), 15013 Denver W Parkway, Golden, United States
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
G3 Stability Challenges and Solutions in metal halide Perovskites materials
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Andres Fabian Gualdron Reyes, Sofia Masi and Teresa S. Ripolles
Invited Speaker, Joseph Luther, presentation 568
Publication date: 15th December 2025

As perovskites near the realm of commercialization, there are still so many unknowns about microscopic effects within the perovskite layer and within the overall device stack. In a typical PIN single junction perovskite solar cell, the hole transport layer (HTL) plays a critical role in serving as the template for which the perovskite crystalizes upon in addition to its intended job to extract the positively charged carriers. At this stage, there are a variety of material classes being used effectively in PIN solar cells including metal oxides, molecular layers and polymers. In this presentation, we will explore the role that these different classes of materials play in the function and stability of perovskite solar cells. In addition, the synergy of multiple HTLs can provide better extraction and stability. We will describe the interplay of double HTLs. On the top surface of the perovskite, passivation and the interface between perovskites and the fullerene are one of the weakest layers in the device design but also show the biggest potential for improvement. We explore stengthening strategies and alternative materials from the traditional C60/BCP combination.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info