Additives to Enhance Efficiency and Stability of PPDT2FBT-based Organic Solar Cells
Hassan Ismail a b, Jose Prince Madalaimuthu a b, Ulrich S. Schubert a b, Harald Hoppe a b
a Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, D-07743 Jena, Germany
b Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller University Jena, Philosophenweg 7a, D-07743 Jena, Germany
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
B2 Strategies to push the efficiency and stability limits of organic photovoltaics at a multiscale
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Ignasi Burgués and Maria Saladina
Oral, Harald Hoppe, presentation 591
Publication date: 15th December 2025

The development of organic solar cells requires simultaneous optimization of photovoltaic performance and long-term thermal stability by controlling the bulk heterojunction nanomorphology, which is often mediated by processing solvents and additives. This study investigates the role of small amphiphilic molecules (AMs) as surfactants in stabilizing the bulk heterojunction morphology of PPDT2FBT:PCBM-based organic solar cells. Our research goal is to understand how the chemical nature of AMs and their interface engineering within the device affect stability and efficiency. We demonstrate that the AM's polar headgroup chemistry is a critical determinant for operational stability, and by strategically applying interface engineering across all major interfaces, we identify optimal scenarios for enhancing both efficiency and device durability. Interface engineering not only improves charge transport and mitigates degradation but also supports large-area fabrication and practical device reliability, addressing prominent challenges for commercialization. These findings provide guidance for future molecular design and interface engineering strategies, contributing to the realization of more robust and reliable organic solar cells.

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