Publication date: 15th December 2025
As Si cells are reaching their fundamental limits, silicon/perovskite tandem solar cells are considered to be the next-generation mainstream technology. These and other perovskite-based tandem solar cells usually rely on wide-bandgap (WBG) mixed halide perovskites. However, these cells are always more or less limited by ion migration and halide segregation (HS), which is a critical factor for operational stability.[1] In this talk, I will discuss the intriguing correlation between HS, ion density, and ionic loss evolution in wide-bandgap perovskite solar cells. This also includes how recovery effects seen in HS segregation relate to a recovery in ion density and ionic losses. Related to this, I will also discuss irreversible ionic losses, which stay “locked-in” after prolonged illumination and are therefore critical for the operational stability. I will then elaborate on strategies to mitigate mobile ion-induced performance degradation. This includes pure-iodine, dimethylammonium (DMA)-stabilized WBG perovskites, which are not only efficient (>22% certified) and stable under maximum power point tracking (T80 lifetimes exceeding 8700 h), but also demonstrate notable performances under combined photothermal stressors (light + 85 °C).
M.S. acknowledges funding support from The Chinese University of Hong Kong (CUHK) through the Vice-Chancellor Early Career Professorship Scheme, the Research Grants Council (RGC) under the NSCF/RGC Joint Research Scheme (N_CUHK414/24), and the Innovation and Technology Commission (ITC) via the ITF Seed Fund (ITS/239/23).
