Minimizing Ionic Losses for Efficient and Stable Wide-Bandgap Perovskite Solar Cells
Ziwei Liu a, Nikhil Kalasariya a, Qifan Feng a, Zhaoyu Lou a, Martin Stolterfoht a
a Electronic Engineering Department, The Chinese University of Hong Kong, Sha Tin N.T., Hong Kong SAR, China
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
G2 Monitoring the degradation mechanisms of photovoltaic devices by optoelectronic characterization
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Enrique H. Balaguera and Emilio J. Juarez-Perez
Invited Speaker, Martin Stolterfoht, presentation 694
Publication date: 15th December 2025

As Si cells are reaching their fundamental limits, silicon/perovskite tandem solar cells are considered to be the next-generation mainstream technology. These and other perovskite-based tandem solar cells usually rely on wide-bandgap (WBG) mixed halide perovskites. However, these cells are always more or less limited by ion migration and halide segregation (HS), which is a critical factor for operational stability.[1] In this talk, I will discuss the intriguing correlation between HS, ion density, and ionic loss evolution in wide-bandgap perovskite solar cells. This also includes how recovery effects seen in HS segregation relate to a recovery in ion density and ionic losses. Related to this, I will also discuss irreversible ionic losses, which stay “locked-in” after prolonged illumination and are therefore critical for the operational stability. I will then elaborate on strategies to mitigate mobile ion-induced performance degradation. This includes pure-iodine, dimethylammonium (DMA)-stabilized WBG perovskites, which are not only efficient (>22% certified) and stable under maximum power point tracking (T80 lifetimes exceeding 8700 h), but also demonstrate notable performances under combined photothermal stressors (light + 85 °C).

M.S. acknowledges funding support from The Chinese University of Hong Kong (CUHK) through the Vice-Chancellor Early Career Professorship Scheme, the Research Grants Council (RGC) under the NSCF/RGC Joint Research Scheme (N_CUHK414/24), and the Innovation and Technology Commission (ITC) via the ITF Seed Fund (ITS/239/23).

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info