Field-modulated quantum dot solids for efficient shortwave-infrared optoelectronics
Se-Woong Baek a, Yujin Jung b
a Korea University, Korea, Republic of
b Yeongnam University
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
D3 Chalcogenide Quantum Dots: Materials and Devices for Infrared Light Harvesting, Sensing and Emission
Barcelona, Spain, 2026 March 23rd - 27th
Organizer: Yongjie Wang
Invited Speaker, Se-Woong Baek, presentation 716
Publication date: 15th December 2025

The urgent demand for high-efficiency infrared photon conversion has underscored the potential of colloidal quantum dots (CQDs) as solution-processable absorbers for advanced optoelectronic applications, including photovoltaics (PVs), thermophotovoltaics (TPVs), and photodetectors (PDs). Nonetheless, the practical deployment of shortwave infrared (SWIR) CQDs has been hindered by persistent challenges in achieving monodisperse particle distributions and complete surface passivation. In this work, we present a ligand-pairing strategy specifically optimized for SWIR CQDs, enabling precise modulation of surface chemistry during both synthesis and post-synthetic ligand exchange. A thiourea-derived precursor with tunable reactivity facilitates the formation of CQDs with enhanced size uniformity and colloidal stability, particularly in the large-size regime. Subsequent surface reconstruction using bifunctional atomic ligands effectively displaces residual amines and passivates the (100) facets, thereby minimizing trap states. The resulting SWIR CQD-based optoelectronic devices demonstrate near-unity internal quantum efficiency and deliver high performance across diverse applications, including PV, TPV, and PD, establishing a new performance benchmark for solution-processed SWIR technologies.

© FUNDACIO DE LA COMUNITAT VALENCIANA SCITO
We use our own and third party cookies for analysing and measuring usage of our website to improve our services. If you continue browsing, we consider accepting its use. You can check our Cookies Policy in which you will also find how to configure your web browser for the use of cookies. More info