Publication date: 15th December 2025
The urgent demand for high-efficiency infrared photon conversion has underscored the potential of colloidal quantum dots (CQDs) as solution-processable absorbers for advanced optoelectronic applications, including photovoltaics (PVs), thermophotovoltaics (TPVs), and photodetectors (PDs). Nonetheless, the practical deployment of shortwave infrared (SWIR) CQDs has been hindered by persistent challenges in achieving monodisperse particle distributions and complete surface passivation. In this work, we present a ligand-pairing strategy specifically optimized for SWIR CQDs, enabling precise modulation of surface chemistry during both synthesis and post-synthetic ligand exchange. A thiourea-derived precursor with tunable reactivity facilitates the formation of CQDs with enhanced size uniformity and colloidal stability, particularly in the large-size regime. Subsequent surface reconstruction using bifunctional atomic ligands effectively displaces residual amines and passivates the (100) facets, thereby minimizing trap states. The resulting SWIR CQD-based optoelectronic devices demonstrate near-unity internal quantum efficiency and deliver high performance across diverse applications, including PV, TPV, and PD, establishing a new performance benchmark for solution-processed SWIR technologies.
