Shortwave-infrared Silver Chalcogenide Colloidal Quantum Dots
Hongchao Yang a
a Suzhou Institute of Nano-Tech and Nano-Bionics Chinese academy of sciences, China
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
D3 Chalcogenide Quantum Dots: Materials and Devices for Infrared Light Harvesting, Sensing and Emission
Barcelona, Spain, 2026 March 23rd - 27th
Organizer: Yongjie Wang
Invited Speaker, Hongchao Yang, presentation 731
Publication date: 15th December 2025

Colloidal semiconductor quantum dots (CQDs) have widely applied in various fields, range from optoelectronic devices to biological imaging, owing to their unique physicochemical properties like size-tunable absorption and fluorescence emission, high photoluminescence (PL) brightness, facile surface functionalization, and well stability. Thereinto, silver chalcogenide CQDs have garnered a considerable interest because of their narrow bandgap and the absence of toxic heavy metal components. However, synthesizing silver chalcogenide CQDs with high absolute PL quantum yields (PLQYs) remains a great challenge. Here, we have developed gold atom doping and surface ligand passivation strategies for silver chalcogenide CQDs, which effectively suppress their nonradiative recombination of excitons, achieving the CQDs with absolute PLQYs exceeding 87%. In addition, we have further explored the CQDs in near-infrared optoelectronic devices. The CQD integrated into light-emitting diodes (LEDs) achieve an external quantum efficiency (EQE) of 15.8% with electroluminescence extending beyond 1000 nm, while their application in photodiodes yields a specific detectivity exceeding 1013 Jones.

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