Frequency-Resolved 2D-g(2) Measurements Reveal Triexciton Features in Cesium Lead Bromide Perovskite Nanocrystals
Hendrik Utzat a
a Massachusetts Institute of Technology (MIT), Massachusetts Avenue, 77, Cambridge, United States
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
H2 Halide perovskites for quantum technologies
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Quinten Akkerman, Simon Boehme and Maksym Kovalenko
Invited Speaker, Hendrik Utzat, presentation 743
Publication date: 15th December 2025

Perovskite quantum dots are now established emitters of non-classical light. We present a single-emitter study using a spectrally dispersed single-photon avalanche diode (SPAD) array to perform highly multiplexed time- and frequency-resolved photon-correlation spectroscopy on individual quantum dots at low temperature.[1] This methodology reveals even complex higher-order many-body dynamics. We report biexciton binding energies and assign their charged states, which undergo fast (µs) switching dynamics. Most notably, we identify a spectral feature blue-shifted from the exciton by 7.4 ± 1.9 meV as the P-type triexciton and establish the order of its cascade emission.

[1] Hinkle, A., Tsao, C., Duell, A., Utzat, H. Multi-Dimensional Photon-Correlations Reveal Triexciton Features in Single Perovskite Quantum Dots. arXiv:2509.12461 (2025). 

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