Publication date: 15th December 2025
Perovskite quantum dots are now established emitters of non-classical light. We present a single-emitter study using a spectrally dispersed single-photon avalanche diode (SPAD) array to perform highly multiplexed time- and frequency-resolved photon-correlation spectroscopy on individual quantum dots at low temperature.[1] This methodology reveals even complex higher-order many-body dynamics. We report biexciton binding energies and assign their charged states, which undergo fast (µs) switching dynamics. Most notably, we identify a spectral feature blue-shifted from the exciton by 7.4 ± 1.9 meV as the P-type triexciton and establish the order of its cascade emission.
[1] Hinkle, A., Tsao, C., Duell, A., Utzat, H. Multi-Dimensional Photon-Correlations Reveal Triexciton Features in Single Perovskite Quantum Dots. arXiv:2509.12461 (2025).
