Liquid Sunlight®, Made from CO2
Peidong Yang a
a Department of Chemistry, Department of Materials Science and Engineering, University of California, Berkeley 94720
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Quinten Akkerman, Josep Albero Sancho, Virgil Andrei, Nikolas Antonatos, Milena Arciniegas, Se-Woong Baek, Simon Boehme, Ankita Bora, Francesca Borghi, Annalisa Bruno, Ignasi Burgués, Stefania Cacovich, Mariano Campoy Quiles, Chia-Chin Chen, Zhuoying Chen, Francesco Chiabrera, Noemí Contreras-Pereda, Miryam Criado-Gonzalez, Kunal Datta, Gustavo de Miguel, Emmanuelle Deleporte, Krishanu Dey, Giorgio Divitini, Johanna Eichhorn, Vida Engmann, Carlos Escudero, María Escudero-Escribano, Karen Forberich, Pol Forn-Díaz, Teresa Gatti, Sixto Gimenez Julia, Paolo Giusto, Andres Fabian Gualdron Reyes, Enrique H. Balaguera, Florian Hausen, Zeger Hens, Yue Hu, Eline Hutter, Ivan Infante, Emilio J. Juarez-Perez, Pascal Kaienburg, Safakath Karuthedath , Jafar Khan, Jiwan Kim, Maksym Kovalenko, Gints Kucinskis, Luis Lanzetta, ZHANZHAO LI, Tom Macdonald, Lorenzo Malavasi, Juan P. Martínez Pastor, Sofia Masi, Diego Mateo Mateo, Shoichi Matsuda, Micaela Matta, Svetlana Menkin, Iván Mora-Seró, Silvia Motti, Christian Müller, Nakita Noel, Soong Ju Oh, Filipa M. Oliveira, Pablo P. Boix, Jay Patel, Fabian Paulus, Sergio Pinilla, Isabella Poli, Marcello Righetto, Teresa S. Ripolles, Carmelita Rodà, Maria Saladina, Oleksandr Savatieiev, Alberto Scaccabarozzi, Nadine Schrenker, Suvodeep Sen, Ji-Youn Seo, Taeseup Song, Ajay Ram Srimath Kandada, Ifan Stephens, Verena Streibel, Albert Tarancón, Magda Titirici, Stefano Toso, Gabriele Tullii, Juan Jesús Velasco Vélez, Yongjie Wang, Jingwen Weng, Robin White, Jiyong Woo, Junzhi Ye, Matteo Zaffalon, Baowei Zhang, Leiting Zhang and Juliette Zito
Oral, Peidong Yang, presentation 856
Publication date: 15th December 2025

Liquid sunlight can be considered as a new form of chemical energy converted and stored in chemical bonds from solar energy. Efficient capture and storage of solar energy can provide unlimited renewable power sources and drive the capture and conversion of greenhouse gases such as CO2 into valuable chemicals. Solar-to-chemical production using a fully integrated system is an attractive goal, but to date, there has yet to be a system that can demonstrate the required efficiency, and durability, or be manufactured at a reasonable cost. One can learn a great deal from natural photosynthesis where the conversion of carbon dioxide and water to carbohydrates is routinely carried out at a highly coordinated system level. There are several key features worth mentioning in these systems: spatial and directional arrangement of the light-harvesting components, charge separation and transport, as well as the desired chemical conversion at catalytic sites in compartmentalized spaces. To design an efficient artificial photosynthetic materials system, at the level of the individual components: better catalysts need to be developed, new light-absorbing semiconductor materials will need to be discovered, architectures will need to be designed for effective capture and conversion of sunlight, and more importantly, processes need to be developed for the efficient coupling and integration of the components into a complete artificial photosynthetic system. In this talk, I will introduce the original nanowire-based photochemical diode system design, and discuss the challenges associated with fixing CO2 through traditional chemical catalytic means, contrasted with the advantages and strategies that biology employs through enzymatic catalysts to produce more complex molecules at higher selectivity and efficiency. Introducing microorganisms as whole-cell electrocatalysts into the overall photochemical diode system led to the generation of powerful photosynthetic biohybrids capable of converting sunlight, H2O, and CO2 into food, fuels, pharmaceuticals, and materials.

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