Publication date: 15th December 2025
Strong photon self-absorption severely limits the performance of metal–halide perovskite X-ray scintillators, leading to reduced light extraction and compromised imaging quality at practical thicknesses. Herein, we report an in situ interfacial growth strategy to construct a hybrid ZnS:Ag–FAPbBr₃ nanocrystal (NC) system embedded in a flexible PVDF matrix, enabling efficient, self-absorption-free scintillation under X-ray excitation. Density functional theory (DFT) and ultrafast spectroscopy confirm rapid Förster resonance energy transfer from ZnS:Ag to FAPbBr₃ within ~20 picoseconds, achieving 83% efficiency. The resulting scintillator films exhibit high imaging resolution (20-line pair mm⁻¹) and a remarkably low detection limit (166 nGy s⁻¹), surpassing the medical diagnostic standard by over 30 times. Moreover, the films maintain more than 90% emission after 604.8 Gy continuous exposure, demonstrating excellent radiation durability. This scalable strategy eliminates self-absorption and enhances the stability of FAPbBr₃ NCs, paving the way for robust, high-sensitivity perovskite scintillators for medical, industrial, and underwater X-ray imaging.
