Self-Absorption-Free Perovskite X-ray Scintillators via Engineered Interfacial Energy Transfer
Shumei Wang a, Omar F. Mohammed a
a Center for Renewable Energy and Storage Technologies (CREST), Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Saudi Arabia
Proceedings of MATSUS Spring 2026 Conference (MATSUSSpring26)
A5 From halide perovskites to perovskite-inspired materials – Synthesis, Modelling and Application
Barcelona, Spain, 2026 March 23rd - 27th
Organizers: Gustavo de Miguel, Lorenzo Malavasi and Isabella Poli
Poster, Shumei Wang, 885
Publication date: 15th December 2025

Strong photon self-absorption severely limits the performance of metal–halide perovskite X-ray scintillators, leading to reduced light extraction and compromised imaging quality at practical thicknesses. Herein, we report an in situ interfacial growth strategy to construct a hybrid ZnS:Ag–FAPbBr₃ nanocrystal (NC) system embedded in a flexible PVDF matrix, enabling efficient, self-absorption-free scintillation under X-ray excitation. Density functional theory (DFT) and ultrafast spectroscopy confirm rapid Förster resonance energy transfer from ZnS:Ag to FAPbBr₃ within ~20 picoseconds, achieving 83% efficiency. The resulting scintillator films exhibit high imaging resolution (20-line pair mm⁻¹) and a remarkably low detection limit (166 nGy s⁻¹), surpassing the medical diagnostic standard by over 30 times. Moreover, the films maintain more than 90% emission after 604.8 Gy continuous exposure, demonstrating excellent radiation durability. This scalable strategy eliminates self-absorption and enhances the stability of FAPbBr₃ NCs, paving the way for robust, high-sensitivity perovskite scintillators for medical, industrial, and underwater X-ray imaging.

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