Publication date: 15th December 2025
The transition toward a sustainable energy landscape requires the development of high-efficiency optoelectronic devices that minimize energy loss and utilize high-performance materials. Semiconductor Quantum Dots (QDs) and their size-dependent optical properties are fundamental to modern optoelectronics. Lead Halide Perovskite Quantum Dots (PQDs) are a breakthrough material for sustainable applications such as next-generation solar cells and low-energy light sources, offering exceptional photoluminescence quantum yields (PLQY) and exciton diffusion coefficients that are up to two orders of magnitude higher than those of conventional II-VI QDs [1].
In solid-state QD films, energy transport is dominated by Föster Resonance Energy Transfer (FRET), a non-radiative mechanism that is critical for the performance of these devices, given the typical insulating nature of surface ligands. Energy transport is usually studied through exciton diffusion, which reveals the presence of different regimes as a function of the film temperature. In these studies, thermal activation and defects are the main parameters proposed to explain the significant decrease of the exciton diffusion (and thus energy transfer) observed above a certain temperature, typically comprised between 100 K to 200 K [2]. Below that temperature, FRET dominates diffusion, and different mechanisms have been proposed to be at the origin of the particular temperature dependence observed [1]. In this work, we use Spectrally-Resolved Time-Resolved Photoluminescence (TRPL) to systematically investigate the different parameters influencing the observed dependence of FRET with temperature [3]. In our to do so, we analyze the exciton decay kinetics in both the donor and acceptor spectral regions at different temperatures to extract the FRET efficiency, and evaluate its correlation with different parameters such as inter-QD distance compression, absorption-emission spectral overlap or oscillator strength. Our findings reveal that the temperature-dependent character of the oscillator strength is a primary factor governing energy transfer efficiency [4]. Understanding this mechanism is a crucial step toward optimizing the performance of QD-based technologies across different operating temperatures.
This research work was funded by the European Commission-NextGenerationEU, through Momentum CSIC Programme: Develop Your Digital Talent, under grant MMT24-ICMS-01.
