Perovskite Solar Cells: Contact, Scaffold and Preparation Methods
Ivan Mora-Sero a
Materials for Sustainable Development Conference (MATSUS)
Proceedings of September Meeting 2016 (NFM16)
Berlin, Germany, 2016 September 5th - 13th
Organizers: Marin Alexe, Enrique Cánovas, Celso de Mello Donega, Ivan Infante, Thomas Kirchartz, Maksym Kovalenko, Federico Rosei, Lukas Schmidt-Mende, Laurens Siebbeles, Peter Strasser, Teodor K Todorov, Roel van de Krol and Ulrike Woggon
Invited Speaker, Ivan Mora-Sero, presentation 202
Publication date: 14th June 2016

Halide Perovskite can be prepared from solution methods at low temperature, and consequently they can be fabricated without large and expensive facilities, can be easily combined with other materials and efficiencies higher than 22% have been certified. However despites the unprecedentedly fast increase of the reported efficiencies, especially in the last four years, the working mechanisms of this kind of devices are not completely understood. As example the cells with the highest efficiency reported presents a thin TiO2 scaffold with a thicker perovskite capping layer, but it is not completely clear why this configuration provides such high efficiency with suppression of hysteresis effect. Transport, recombination, injection at the contacts or J-V curve hysteresis are strongly dependent on the cell configuration, as the use of scaffold, the perovskite and contact materials and also on the growth conditions. In this talk, I analyze the effect in the solar cell performance of different electron selective contacts and of surface engineering by the addition of self assembly monolayers. In addition, I show the effect of different scaffold configuration in the properties of the device by a systematic optoelectronic characterization, with especial attention to injection properties. I will also analyze the use of additives for the preparation of perovskite thin films.



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