Ensemble and Single Particle Studies of the Fluorescence Properties of core-shell CdSe Nanocrystals with Different Shells and Surface Chemistries
Ute Resch-Genger a, Florian Weigert a, Christian Würth a, Christian Strelow b, Alf Mews b, Christopher Wolter b, Chris Guhrenz c, Nikolai Gaponik c, Alexander Eychmüller c, Pavel Samokhvalov d, Igor Nabiev d
a Bundesanstalt für Materialforschung und -prüfung, Biophotonics, Richard-Willstätter-Straße, 11, Berlin, Germany
b Chemistry, University of Hamburg, D- 20146 Hamburg, Germany, University of Hamburg, D- 20146, Germany
c Physical Chemistry, Technical University (TU) Dresden, DE, Bergstraße 66b Erich-Müller-Bau, Germany
d National Research Nuclear University MEPHI, Kashirskoe shosse, 31. 115409, Moscow, Russian Federation
Materials for Sustainable Development Conference (MATSUS)
Proceedings of September Meeting 2016 (NFM16)
Berlin, Germany, 2016 September 5th - 13th
Organizers: Marin Alexe, Enrique Cánovas, Celso de Mello Donega, Ivan Infante, Thomas Kirchartz, Maksym Kovalenko, Federico Rosei, Lukas Schmidt-Mende, Laurens Siebbeles, Peter Strasser, Teodor K Todorov, Roel van de Krol and Ulrike Woggon
Poster, Florian Weigert, 125
Publication date: 14th June 2016

The optical properties of semiconductor nanocrystals (SCNC) are controlled by constituent material, particle size, and surface chemistry, specifically the number of dangling bonds favoring nonradiative deactivation, and hence also by particle synthesis. In this respect, the fluorescence properties of core-shell CdSe SCNCs with different shells and surface chemistries were studied on ensemble and single particle level, using steady state and time-resolved fluorometry and confocal microscopy with time correlated single photon counting detection. Special emphasis was dedicated to correlate ensemble photoluminescence (PL) quantum yields and decay kinetics with particle brightness, PL time traces, and the On-time fraction of the single SCNCs. Additionally, the confocal PL images were correlated with AFM measurements in order to derive the amount of absorbing, yet non-emisssive ”dark” SCNCs, the presence of which leading to an underestimation of ensemble PL quantum yields. The results of this study can help to identify synthetic routes and surface modifications minimizing the fraction of dark SCNC, thereby closing the gap to the ultimate goal of colloidally and photochemically stable SCNCs with a PL quantum yield of close to unity.



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