Characterization of Transport and Recombination in Perovskite Solar Cells by Impedance Spectroscopy
Iván Mora-Seró a
a Universitat Jaume I, Institute of Advanced Materials (INAM) - Spain, Avinguda de Vicent Sos Baynat, Castelló de la Plana, Spain
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting19 (NFM19)
#PERFuDe19. Halide perovskites: when theory meets experiment from fundamentals to devices
Berlin, Germany, 2019 November 3rd - 8th
Organizers: Claudine Katan, Wolfgang Tress and Simone Meloni
Invited Speaker, Iván Mora-Seró, presentation 109
DOI: https://doi.org/10.29363/nanoge.nfm.2019.109
Publication date: 18th July 2019

Recombination is a key parameter to stablish the performance of a Solar Cell and stablish their limitations for a further optimization process. On the other hand, charge transport processes are usually not considered in the limitation of perovskite solar cell performance as 3D halide perovskites presents good transport properties. However, selective contact or the use of bulky cations in 2D/3D perovskite can also introduce a transport limitation in the cell performance. These parameters can be easily determined in other kind of solar cells as in dye sensitized solar cells (DSSCs) by impedance spectroscopy, but in the case of Perovskite Solar Cells (PSCs) this determination have been elusive. Impedance spectroscopy is a non-destructive characterization technique that can help in the understanding of these devices. Impedance spectroscopy is a characterization method in the frequency domain that allows to decouple physical processes with different characteristic times at the working conditions i.e. under illumination and applied bias. In this talk we show as solar cells using mesoporous TiO2scaffold can behave as DSSCs when the amount of deposited perovskite is low enough. As the amount of perovskite in the cell increases the behavior resembles the observed for PSCs. The analysis by impedance spectroscopy of these samples have allow as to connect both kind of devices and determine that transport and recombination are coupled in PSCs. Despite this limitation we show different examples in which impedance spectroscopy provide an excellent guide to determine the limiting processes in different kind of PSCs, providing consequently important clues to experimentalist to optimize its performance.

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