Phase Behavior, Miscibility, and Stability of Non-Fullerene Organic Solar Cells
Harald Ade a
a North Carolina State University, Partners Way, 911, Raleigh, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting19 (NFM19)
#OPV19. Organic Photovoltaics: recent breakthroughs, advanced characterization and modelling
Berlin, Germany, 2019 November 3rd - 8th
Organizers: Jörg Ackermann and Uli Würfel
Invited Speaker, Harald Ade, presentation 112
DOI: https://doi.org/10.29363/nanoge.nfm.2019.112
Publication date: 18th July 2019

The organic solar cell (OSC) field has been revolutionized by the development and use of novel non-fullerene small molecular acceptors with efficiencies now reaching >16% in several systems. Many reports of OSC blends focus primarily on the device performance aspect of the solar cell and the device stability and mechanical durability of non-fullerene OSCs have received less attention. Developing devices with both high performance and long-term stability remains a challenge, particularly if the material choice is restricted by roll-to-roll and benign solvent processing requirements and by desirable ductility requirements. Yet, morphological and mechanical stability is a prerequisite for OSC commercialization. We will discuss the current understanding of the phase behavior of OSC mixtures and the relation of phase behavior to performance, processing needs (e.g., kinetic quench), and morphological stability via meta-stability or vitrification. A large range of miscibility (from hyper-miscibility to strong hypo-miscibility) is observed in a number of systems, including a temperature dependence that can be a complex mixture of upper- and lower critical solution temperature behavior for both the binodal and the liquidus. The measurements and concepts presented should help to create molecular structure-function relationships that would allow some predictive guidance on how desired phase behavior and vitrification properties can be targeted by specific chemical design, and how simple measurements such as differential calorimetry can be used to screen properties that impact stability.

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