Advances in Multimodal Scanning Probe Microscopy at the Nanoscale
Rajiv Giridharagopal a, David Ginger a
a University of Washington, US, Seattle, United States
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting19 (NFM19)
#MapNan19. Mapping Nanoscale Functionality with Scanning Probe Microscopy
Berlin, Germany, 2019 November 3rd - 8th
Organizer: Stefan Weber
Oral, Rajiv Giridharagopal, presentation 125
DOI: https://doi.org/10.29363/nanoge.nfm.2019.125
Publication date: 18th July 2019

The recent combination of functional scanning probe microscopy with data science techniques has started to yield interesting new insights into a wide range of materials. Large multimodal datasets comprising many different measurements on the same area can reveal structure-function relationships beyond that of any single technique. As an example, combining photoluminescence mapping with electrical current measurements in conductive atomic force microscopy shows how the perovskite-electrode contact affects functional solar cells by correlating optical properties with electrical function. Such multidimensional approaches are particularly attractive given the recent emergence of techniques like photoinduced force microscopy (PiFM) that can measure vibrational spectroscopy with nanometer spatial resolution, thereby combining chemical and electrical information. In this talk I will discuss our recent work in functional imaging of materials using data-driven scanning probe methods, from sub-microsecond time-resolved electrostatic force microscopy (trEFM) to multimodal analysis using hyperspectral PiFM. These methods allow for investigation into spatially-dependent properties of nanostructured photovoltaics, such as the nature of grain boundaries in perovskite active layers. While I will focus primarily on hybrid organic-inorganic perovskites, I will also discuss how these techniques reveal new insight into mixed ionic-electronic conductors and nanostructured polymers.

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