Stability of Oxidized Spiro-MeOTAD Under Influence of Perovskite and its Components
Ernestas Kasparavičius a, Tadas Malinauskas a, Vytautas Getautis a
a Faculty of Chemical Technology, Kaunas University of Technology, Lithuania, Radvilėnų plentas, 19, Kaunas, Lithuania
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting19 (NFM19)
#PERFuDe19. Halide perovskites: when theory meets experiment from fundamentals to devices
Berlin, Germany, 2019 November 3rd - 8th
Organizers: Claudine Katan, Wolfgang Tress and Simone Meloni
Poster, Ernestas Kasparavičius, 377
Publication date: 18th July 2019

World energy consumption has been gradually increasing past 50 years and limited sources of fossil fuels are exacting the research on sustainable and renewable energy resources. The conversion of sunlight into electricity is one of the most attractive alternatives for increasing energy demands. Photovoltaic systems could potentially be future electricity generation source with significantly reduced negative impact on environment. [1] Due to simple manufacturing and good performance prospects perovskite solar cells received growing interest from research community. As a result of rapid development in this field, perovskite photovoltaic systems have reached efficiency of 23.7% [2].

Despite relatively high performance of perovskite solar cell (PSC), the current conditions still do not meet the requirement for commercialization. There are three main stability issues with PSCs: environmental (moisture and oxygen), photo and thermal stability. In addition, selective contacts and additives in HTM can also have influence on stability [3,4] .

Charge-transporting materials has been developed for use in perovskite solar cells and vast majority of them require the use of chemical doping as an essential step for preparation of efficient devices. Oxidized 2,2´,7,7´-tetrakis(N,N-di-p-methoxyphenylamine)-9-9´-spirobifluorene (Spiro-MeOTAD) could be one of the potential weak links in the perovskite solar cell composition. Interestingly, very little investigation is done concerning the oxidized HTMs applied in the PSC and their roperties.[3]

 

In this work oxidized spiro-OMeTAD, have been investigated under various conditions in order to estimate influence of temperature, different additives and ion migration from perovskite surface on stability of oxidized spiro-OMeTAD.

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