Directing the structure and electronics of printed hybrid films
Tobias Kraus a b
a INM - Leibniz Institute for New Materials, Campus D2 2, Saarbrücken, Germany
b Colloid and Interface Chemistry, Saarland University, Saarbrücken Campus, Saarbrücken, Germany
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2021 (NFM21)
#NCFun21. Fundamental Processes in Nanocrystals and 2D Materials
Online, Spain, 2021 October 18th - 22nd
Organizers: Brandi Cossairt and Jonathan De Roo
Invited Speaker, Tobias Kraus, presentation 058
DOI: https://doi.org/10.29363/nanoge.nfm.2021.058
Publication date: 23rd September 2021

We study liquid inks that form hybrid functional electronic films when drying. The interplay between organic and inorganic components affects structure and electronic properties. In this talk, I will focus on the case of metal or semiconductor particles and discuss how non-polar organic shells change their agglomeration and assembly into dielectric films [1].

Experiments that monitor the agglomeration and self-assembly in non-polar dispersions allow us to follow the film formation of spherical and anisometric particles. Systematic variation of the geometry of spherical particles with metal or semiconductor cores and dense alkyl shells indicate a transition between core- and shell-dominated assembly of non-polar dispersions that I will outline [2]. The comparison of spherical particles with ultrathin wires indicates that entropic effects strongly depend on solvent molecule geometry and that they can induce nanowire agglomeration or “bundling” [3]. Comparatively little is known on the assembly of highly concentrated dispersions. I will introduce new types of experiments that probe this regime using small, evaporating droplets of dispersions that we bring into the X-ray beam of a small-angle beamline [4].

Complexity increases when using electronically conductive organic shells on inorganic particles. I will briefly discuss hybrids of gold spheres that are coated with polythiophenes. The molecular arrangement of the monomer units on the metal surface depends on the core geometry and affects bulk conductivity [5].

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