The Genesis and Rise of Mesoscopic Photovoltaics and Perovskite Solar Cells
Michael Graetzel a
a Ecole Polytechnique Federale de Lausanne (EPFL), Lausanne, Switzerland
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2021 (NFM21)
Online, Spain, 2021 October 18th - 22nd
Organizers: Bastian Mei, Eva Unger, Shweta Agarwala, Ardalan Armin, Maya Bar Sadan, Karen Chan, Moritz Futscher, L. Jan Anton Koster, Maksym Kovalenko, Linn Leppert, Michael Saliba, Stefan Weber, Uli Würfel, Jörg Ackermann, Stefano Agnoli, Mahshid Ahmadi, Derya Baran, Brandi Cossairt, Jonathan De Roo, Marina Filip, Feng Gao, Sophia Haussener, Jan Philipp Hofmann, Ivan Infante, Jovana Milic, Brian Rodriguez, Victor Sans Sangorrin, Juliane Borchert, María Escudero-Escribano, Aditya Mohite, Lea Nienhaus, Brian Seger and Zdenek Sofer
Keynote, Michael Graetzel, presentation 175
DOI: https://doi.org/10.29363/nanoge.nfm.2021.175
Publication date: 23rd September 2021

Recently molecular photovoltaics, such as dye sensitized cells (DSCs) and perovskite solar cells (PSCs) have emerged as credible contenders to conventional p-n junction photovoltaics. Their certified power conversion efficiency currently attains 25.5 %, exceeding that of the market leader polycrystalline silicon. This lecture covers the genesis and recent evolution of DSCs and PSCs, describing their operational principles and current performance. DSCs have meanwhile found commercial applications for ambient light harvesting and glazing producing electric power from sunlight. The scale up and pilot production of PSCs are progressing rapidly but there remain challenges that still need to be met to implement PSCs on a large commercial scale. PSCs can produce high photovoltages rendering them attractive for applications in tandem cells, e.g. with silicon and as power source for the generation of fuels from sunlight. Examples to be presented are the solar generation of hydrogen from water and the conversion of CO2 to chemical feedstocks such as ethylene, mimicking natural photosynthesis.

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