Effect of intra-octahedra distortions on optical properties by substitutions of mono, trivalent cations, and halide anions in halide double perovskites
Mala Maruthi a, Tamilselvan Appadurai a, Aravind Kumar Chandiran a
a Indian Institut of Technology Madras, ESB002, Chennai, India
Materials for Sustainable Development Conference (MATSUS)
Proceedings of nanoGe Fall Meeting 2021 (NFM21)
#PerEmer21. Perovskites III: Emerging Materials and Phenomena
Online, Spain, 2021 October 18th - 22nd
Organizers: Moritz Futscher, Jovana Milic and Aditya Mohite
Contributed talk, Mala Maruthi, presentation 193
DOI: https://doi.org/10.29363/nanoge.nfm.2021.193
Publication date: 23rd September 2021

Halide double perovskites (A2B’B”X6) have recently shown broadband emission in a single component and attracted various light-emitting device applications. Generally, in these double perovskites, valance and conduction bands are predominately obtained by mono (B’), trivalent (B”) cations, and halogen(X). In this work, we carried out systematically band engineering by distorted octahedra by substituted with mono (Na+), trivalent (In3+) cations, and halide anion (Cl-) and explored their structural, optical properties behavior of the cubic double perovskites Cs2AgBiBr6. In the undoped parent compound, only very weak photoluminescence is observed, but in substitution of Na, In, Cl samples broadband emission peak centered at around 620nm. In addition to this, the substitution of In3+ (25%) and Cl- (100%) showed increased lifetime compared to host material, and comparison of excitation and absorption spectra indicates that all the doped and undoped materials have shown indirect bandgap materials. 

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