Perovskite-Inspired Materials for Indoor Photovoltaics
Robert Hoye a
a Inorganic Chemistry Laboratory, University of Oxford, UK
NIPHO25
Proceedings of International Conference on Perovskite Thin Film Photovoltaics and Perovskite Photonics and Optoelectronics (NIPHO25)
Cagliari, Italy, 2025 June 9th - 10th
Organizers: Giulia Grancini, Daniela Marongiu and Aldo Di Carlo
Invited Speaker, Robert Hoye, presentation 007
Publication date: 24th April 2025

A substantial effort has been made over the past decade to develop lead-free alternatives to halide perovskites that could emulate their exceptional optoelectronic properties, but overcome their stability and toxicity limitations. Many of these perovskite-inspired materials are visible light absorbers, and a promising application is indoor light harvesting [1]. This talk discusses our recent work on two such materials for indoor photovoltaics: BiSBr and Sb2S3. BiSBr is novel light absorber [2]; Sb2S3 has been developed for solar cells, but its development for indoor photovoltaics hasjust begun [3]. We show both materials to be stable in air, and for Sb2S3, we achieve large-grained films with compact morphology through hydrothermal growth with monoethanoamine additives. By lowering the grain boundary density, we achieve increases in open-circuit voltage to 0.8 V under 1-sun illumination [2]. For IPVs, we achieve 17.55% power conversion efficiency under 3000 K white light emitting diode illumination (1000 lx), and create 5 cm2-area minimodules to demonstrate their applications in powering a multisensory platform used for IoT [3]. This places Sb2S3 IPVs among the most efficient for pnictogen-based semiconductors, and the devices were also stable for at least a month of testing without encapsulation [3].

To finish this talk, I will discuss the debate in the growing community working on emerging materials for IPV around a consensus in performance measurement. I focus on the open questions and possible solutions being proposed, as well as future pathways.

R. L. Z. Hoye thanks the UK Research and Innovation for funding through a Frontier Grant (no. EP/X029900/1), awarded through the 2021 ERC Starting Grant Scheme. We also thank EPSRC for funding (no. EP/V014498/2), as well as the Royal Academy of Engineering through the Senior Research Fellowship scheme (no. RCSRF/2324-18-68).

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