Perovskite-CIGS 4T Tandem Solar Cells with Thin IZO Rear Electrodes
Moritz Loy a, Erik Ahlswede a
a Zentrum für Sonnenenergie‐ und Wasserstoff‐Forschung Baden‐Württemberg (ZSW) Stuttgart, Germany, Meitnerstraße, 1, Stuttgart, Germany
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Online nanoGe Fall Meeting 20 (OnlineNFM20)
#PerFun20. Perovskite I: Solar Cells and Related Optoelectronics
Online, Spain, 2020 October 20th - 23rd
Organizers: Mónica Lira-Cantú and Mohammad Nazeeruddin
Poster, Moritz Loy, 232
Publication date: 4th October 2020
ePoster: 

Four terminal (4T) tandem solar cells generally suffer from parasitic absorption in their three obligatory transparent electrodes. Using highly optimized transparent conductive oxides (TCOs) such as hydrogen-doped indium oxide (IO:H) as electrode materials can reduce the parasitic absorption. [1] However, the sensitive layers of the perovskite cell limit the freedom of choice for the rear electrode to materials that are softly processed at low temperatures. Room-temperature-sputtered indium zinc oxide (IZO) is a suitable rear electrode material, but exhibits non-ideal absorption in the near-infrared. This study investigates, how reducing the thickness of the IZO electrode benefits the power conversion efficiency (PCE) of 4T perovskite-CIGS tandem solar cells. A metal finger-shaped grid on the rear of the 0.5 cm² sized perovskite top cell compensates for the resistive losses in the thinned IZO layers. Reducing the rear electrode thickness from 162 nm down to 54 nm and 34 nm significantly improves the transmittance of the top cell to over 90% maximum while maintaining its PCE at over 15%. With this approach we are able to push the PCE of the complete 4T perovskite-CIGS tandem device up to 23.8%.

This project has received funding from the European Union‘s Horizon 2020 research and innovation programme under grant agreement N° 850937 PERCISTAND and from the Federal Ministry of Economic Affairs and Energy under contract No 03EE1038A CAPITANO.

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