Eco-Friendly Spray Deposition of Perovskite Films on Macroscale Textured Surfaces
Simone Sansoni a, Michele De Bastiani b, Erkan Aydin b, Esma Ugur b, Furkan Halis Isikgor b, Areej Al-Zahrani b, Francesco Lamberti a, Frederic Laquai b, Moreno Meneghetti a, Stefaan De Wolf b
a University of Padova, Department of Chemical Sciences, Via Francesco Marzolo, 1, Padova, Italy
b Department of Physical Sciences and Engineering, KAUST Solar Centre (KSC), Saudi Arabia, Saudi Arabia
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Online nanoGe Fall Meeting 20 (OnlineNFM20)
#PerFun20. Perovskite I: Solar Cells and Related Optoelectronics
Online, Spain, 2020 October 20th - 23rd
Organizers: Mónica Lira-Cantú and Mohammad Nazeeruddin
Poster, Simone Sansoni, 250
Publication date: 4th October 2020
ePoster: 

An innovative sequential eco-friendly spray coating (SEF-SC) technique is developed to uniformly deposit metal halide perovskite films on macroscale textured surfaces, such as textured crystalline-silicon wafers. Contrasting with previous work on spray-coated perovskite solar cells, the method presented in this work completely avoids the use of toxic and dangerous solvents. Both MAPbI3 and CsFAMAPbI3−xBrx perovskite films deposited by SEF-SC show excellent optoelectronic properties and no phase segregation, even when synthesized in ambient conditions. Uniform perovskite coatings are obtained on textured-silicon heterojunction solar cells underlining the promise of this method, which holds the potential for scalable wet processing of perovskites on rough substrates, such as for low-cost perovskite/silicon tandem solar cell fabrication.

The research reported in this publication was supported by funding from King Abdullah University of Science and Technology (KAUST) under award no. OSR-CARF URF/1/3079-33-01 and the project OPERA of the Interdepartmental Centre Giorgio Levi Cases for Energy Economics and Technology, University of Padova.

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