Moving Ions Vary Electronic Conductivity in Lead Bromide Perovskite Single Crystals through Dynamic Doping
Marisé Garcia-Batlle a, Oriane Baussens b, Smaïl Amari c, Eric Gros-Daillon b, Jean-Marie Verilhac c, Julien Zaccaro c, Antonio Guerrero a, Germà Garcia-Belmonte a
a Universitat Jaume I, Institute of Advanced Materials (INAM) - Spain, Avinguda de Vicent Sos Baynat, Castelló de la Plana, Spain
b Grenoble Alpes University CEA LITEN, France
c Grenoble Alpes University CEA LETI, F38000, Grenoble, France
Materials for Sustainable Development Conference (MATSUS)
Proceedings of Online nanoGe Fall Meeting 20 (OnlineNFM20)
#PerEmer20. Perovskite III: Emerging Metal Halide Semiconductors
Online, Spain, 2020 October 20th - 23rd
Organizers: Dmitry Dirin, Jacky Even and Constantinos Stoumpos
Poster, Marisé Garcia-Batlle, 275
Publication date: 4th October 2020
ePoster: 

Metal halide perovskite single crystals are being explored as functional materials for a variety of optoelectronic
applications but a general uncertainty exists about the relevant mechanisms governing the electronic operation The
presence of mobile ions and how these defect species alter the internal electrical field, interact with the contact
materials or modulate electronic properties is highlighted Here a set of high quality thick MAPbBr 3 single
crystals contacted with low reactivity chromium electrodes are analyzed by impedance spectroscopy The
examination of the sample resistance evolution with bias and releasing time, reveal an interplay between the
perovskite electronic conductivity and the defect distribution within the crystal bulk

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