Unveiling the Additive-Assisted Oriented Growth of Perovskite Crystallite for High Performance Light-Emitting Diodes
Nana Wang a
a Nanjing Tech University, Xin Mo Fan Ma Lu, 5, Nanjing Shi, China
Proceedings of Applied Light-Matter Interactions in Perovskite Semiconductors 2021 (ALMIPS2021)
Online, Spain, 2021 October 5th - 7th
Organizers: Rafael Sánchez Sánchez and Miguel Anaya
Invited Speaker, Nana Wang, presentation 009
DOI: https://doi.org/10.29363/nanoge.almips.2021.009
Publication date: 23rd September 2021

Solution-processed metal halide perovskites have been recognized as one of the most promising semiconductors, with applications in light-emitting diodes (LEDs), solar cells and lasers. Various additives have been widely used in perovskite precursor solutions, aiming to improve the formed perovskite film quality through passivating defects and controlling the crystallinity. The additive's role of defect passivation has been intensively investigated, while a deep understanding of how additives influence the crystallization process of perovskites is lacking. Here, we reveal a general additive-assisted crystal formation pathway for FAPbI3 perovskite with vertical orientation, by tracking the chemical interaction in the precursor solution and crystallographic evolution during the film formation process. The resulting understanding motivates us to use a new additive with multi-functional groups, 2-(2-(2-Aminoethoxy)ethoxy)acetic acid, which can facilitate the orientated growth of perovskite and passivate defects, leading to perovskite layer with high crystallinity and low defect density and thereby record-high performance NIR perovskite LEDs (~800 nm emission peak, a peak external quantum efficiency of 22.2% with enhanced stability).

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