Biocellulose-YVO4:Er3+-Ho3+ nanoparticles composite membranes. Infrared to visible up-conversion and activation of PDT processes
Sidney J.L. Ribeiro a, Karina Nigoghossian a, Edison Pecoraro a, Antonio C. Tedesco b, Fernando L. Primo b, Maristela F.S. Peres b
a Institute of Chemistry- São Paulo State Univ, Unesp- CP 355, Araraquara, SP, 14801-970
b Center for Nanotechnology and Tissue Engineering, Photobiology & Photomedicine Research Group, São Paulo University-FFCLRP-DQ, Ribeirão Preto, SP, 14040-901
Invited Speaker, Sidney J.L. Ribeiro, presentation 016
Publication date: 10th April 2014

YVO4:(Yb3+-Er3+/Ho3+) nanoparticles (NPs) were incorporated in bacterial cellulose membranes obtained from Gluconacetobacter xylinus. Materials present the property of converting near-infrared (NIR) into higher-energy visible light. NPs were prepared by optimizing towards higher emission intensity at the wavelength range of absorption of Chloroaluminum phthalocyanine (ClAlPc) used as photosensitizer in Photodynamic Therapy. The NIR excitation wavelength is advantageous for application in biological systems, as it allows deeper penetration into tissues than the UV-visible radiation commonly used for luminescence excitation. Upconversion emission spectra obtained under excitation at 980 nm showed preferential green emission for the Yb3+-Er3+ system and red emission for the Yb3+-Ho3+ one. In the last case, by using mixtures of aqueous suspensions of the nanoparticles and ethanolic solutions of ClAlPc the red emission (680nm) of the phtalocyanine was observed through excitation by the upconverted emission of the nanoparticles (650nm) which were excited in NIR (980nm).

Keywords: Upconversion, biocellulose, Chloroaluminum phthalocyanine, yttrium vanadate nanoparticles;



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