Upconversion Nanoparticles: Materials, Mechanism and Modeling
Andries Meijerink a, Freddy Rabouw a, Rosa Martin Rodriguez a
Invited Speaker, Andries Meijerink, presentation 018
Publication date: 10th April 2014

Upconversion in nanoparticles is a field of research that is rapidly gaining importance due to new areas of applications, viz. biomedical imaging and spectral conversion for solar cells. In this presentation new efficient upconversion materials will be discussed based on the well known Er3+-Yb3+ couple as well as the potential of other lanthanide ion combinations [1-3]. Upconversion of IR to NIR radiation has been widely explored for application in c-Si solar cells with a bandgap around 1100 nm. Even larger gains are possible in photovoltaic applications based on wider bandgap materials. For example, for a 750 nm large bandgap solar cell like amorphous Si, upconversion can increase the efficiency by more than 70% for a maximum UC quantum efficiency of 50% (see Figure 1). The potential of upconversion nanoparticles is related to the possibility to make transparent upconversion materials due to the absence of light scattering by nanoparticles of sizes well below the wavelength of light. A disadvantage is the lower efficiency of upconversion in nanoparticles. To understand the efficiency and efficiency losses, upconversion mechanism will be discussed, including modeling of energy transfer processes in confined (nano) geometries [4]. Finally the option of sensitized upconversion will be explored giving an outlook on the future applications of UC-nanoparticles for application in solar cells and bio-imaging.  

 

Figure 1. Potential efficiency gain of down- and upconversion for an a-Si solar cell. 

 

[1] J. de Wild, A. Meijerink, J. K. Rath, W. G. J. H. M. van Sark and R. E. I. Schropp Energy & Environmental Science 4, 4835--4848 (2011).

[2] R. Martín-Rodríguez, S. Fischer, A. Ivaturi, B. Froehlich, K. W. Krämer, J. C. Goldschmidt, B. S. Richards and A. Meijerink Chemistry of Materials 25, 1912--1921 (2013).

[3] R. Martín-Rodríguez and A. Meijerink Journal of Luminescence 147, 147 - 154 (2014).

[4] F.T. Rabouw, S.A. den Hartog, T. Senden, A. Meijerink, Nature Communications, in press



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