An attempt to improve the photovoltaic performance of pyrrole-based dyes by adjusting isolation groups
Zhen li a, Huiyang li a, Runli Tang a, Qianqian li a, hongwei han b
a Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan University, Wuhan, 430072, China
b Huazhong University of Science and Technology, Michael Grazel Center for Mesoscopic Solar Cells, Wuhan National Laboratory for Optoelectronics, Wuhan, 430072, China
International Conference on Hybrid and Organic Photovoltaics
Proceedings of 6th International Conference on Hybrid and Organic Photovoltaics (HOPV14)
Ecublens, Switzerland, 2014 May 11th - 14th
Organizers: Michael Graetzel and Mohammad Nazeeruddin
Poster, Qianqian li, 030
Publication date: 1st March 2014

 

Four new pyrrole-based organic sensitizers with different isolation groups were conveniently synthesized and applied to dye sensitized solar cells (DSCs).The introduction of isolation group could suppress dye aggregates and electron recombination, and the various isolation groups with different size could vary the photovoltaic performance of the corresponding dyes in a large degree. Especially, when two pieces of D-π-A chromophore moieties shared one isolation group to construct the "H" type dye, the conversion efficiency increased largely. Consequently, in the corresponding solar cell of LI-57 with the "H" structure, a short-circuit photocurrent density (Jsc)was tested to be 13.85 mA cm−2,while 0.72 V for the open-circuit photovoltage (Voc), and 0.64 for thefill factor (FF),and 6.43% for the overall conversion efficiency (η), exceeding its analogue LI-55 (5.94%) with the same isolation group. These results demonstrated that both the size (bulk and shape) and the linkage mode between the D-π-Achromophores and the isolation groups, could influence their photovoltaic performance, providing a new approach to optimize the chemical structure of dyes to achieve high conversion efficiencies.


Fig.1 the structure of pyrrole-based dyes
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